If you scoff at my food you will be asked to leave. Scoff is a real legitimate word in real dictionaries. Scarf as a verb is an old commonly used but not entirely respectable word.
Scarf is something you wear around your neck on a cold inter day.
http://www.dictionary.com/browse/scarf
http://www.dictionary.com/browse/scoff
If you follow the derivation, "scoff" was also a noun for "food" or "grub".
And a footnote offers an explanation for the mutation to "scarf":
1955-60, Americanism; variant of "scoff", with r inserted probably through r-dialect speakers' mistaking the underlying vowel as an r-less ar
I scoff at your desire to scarf the entire buffet. /S