For the Harrier, they are indeed explosives in the case of an ejection. However, ejection-seat based helicopters have not yet come into fruition...
Cool, I always wondered what those were for.
I just realized that ejecting upwards would be a bit problematic if the blades are still there...
Need more coffee.
I am no engineer but I would assume that putting ejection seats on a helicopter might be a BAD idea.
“For improved pilot survivability the Ka-50 is fitted with a NPP Zvezda (transl. Star) K-37-800 ejection seat, which is a rare feature for a helicopter.[20] Before the rocket in the ejection seat deploys, the rotor blades are blown away by explosive charges in the rotor disc and the canopy is jettisoned.[21]”
http://en.wikipedia.org/wiki/Kamov_Ka-50