The probability of VP becoming President is remote.
VPs go to foreign funerals and they don’t have any role in decision making. They are only good for publicity (e.g. clearly articulating and defending the policies).
In some case, President really respects the VP (e.g. Bush-Cheney) so they have influence, but this has nothing to do with the role of VP itself.
Two brothers grew up and chose careers. One became a sailor and went to sea. One became vice-president. Neither one was ever heard from again.
I just know I wouldn't want Romney to be VP because I don't want any chance of him becoming President one day.