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To: Wonder Warthog
In cracking situations you have a large number of different products forming simultaneously, including some with longer chains than the starting material.

You have a vastly different understanding of the cracking process than I learned from the Chemical Engineers at the engineering firm that designs thermal crackers.

79 posted on 04/18/2011 7:30:36 PM PDT by thackney (life is fragile, handle with prayer (biblein90days.org))
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To: thackney
"You have a vastly different understanding of the cracking process than I learned from the Chemical Engineers at the engineering firm that designs thermal crackers."

Chemical engineers who design thermal crackers have a VERY limited field of view of chemistry. Think about the various polymerization processes, for instance for polyethylene. Pure pressure and temperature (VERY high), with a free radical initiator (no catalyst) in ethylene yields a polymer. A different set of conditions (in solution, with catalyst) yields a very different material. Yet another set of conditions with a slightly different catalyst yields still a third product, with vastly different properties.

The process in the article apparently is more similar to polymerization than "cracking".

80 posted on 04/19/2011 3:38:33 AM PDT by Wonder Warthog
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