The street level Google earth pictures of this property may give more detail: http://maps.google.com/maps?q=800+a+street+se+washington+dc&oe=utf-8&rls=org.mozilla:en-US:official&client=firefox-a&um=1&ie=UTF-8&hq=&hnear=800+A+St+SE,+Washington+D.C.,+DC+20003&gl=us&ei=ipFUTcGiEMXZgQfrhLXiCA&sa=X&oi=geocode_result&ct=title&resnum=1&ved=0CBMQ8gEwAA
The one from above shows their second car parked diagonally so that one would have to leave the garage at an angle..
But that leaves the question of why the door was closed and raises the question of why this anti-freeze-headlight theory was put forward by the authorities. Fire investigators for fire departments are usually pretty good and it shouldn't be that hard to find the ignition point and the initial accelerant.
One possibility I overlooked for a stairway and entry into the garage would be from the basement level up to the garage. But the entry door on that stoop would seem to rule that out. The headroom for that stairway would impinge on what we've been calling a mudroom behind the door on that stoop.