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Gasification may be key to U.S. ethanol
AP ^ | 03/04/07 | DIRK LAMMERS

Posted on 03/04/2007 5:03:09 PM PST by nypokerface

SIOUX FALLS, S.D. - The government awarded $385 million in grants last week aimed at jumpstarting ethanol production from nontraditional sources like wood chips, switchgrass and citrus peels. What's surprising is that half of the six projects chosen will use a process first discovered almost a century ago to turn coal into a gas.

President Bush set a goal in his State of the Union address of producing 20 percent of the nation's fuel supply from renewable resources by 2017. Much of those supplies will come from the conversion of corn into enthanol, fueled by a boom in new ethanol plant construction that's already under way.

But Thursday's forecast from the Agriculture Department that half of this year's U.S. corn crop will be consumed by ethanol producers has raised red flags. Critics say surging demand for corn could push up prices of everything from corn-sweetened soft drinks to meats, since corn is a common feed ingredient for livestock.

That helps explain why the Energy Department is placing a big bet on a process called gasification. Long hailed as a more environmentally friendly way to turn coal into electricity, the process might also provide a faster and eventually cheaper way to produce ethanol from a variety of renewable sources collectively known as biomass, some scientists say.

For corn-based ethanol plants, the process of producing ethanol is as simple as brewing beer: sugars are extracted from the corn kernels and then enzymes are added to ferment it into alcohol. But biomass feedstocks don't easily give up their starches, so more expensive steps are needed to ferment cellulose in high-pressure chambers that have limited amounts of oxygen, according to Lanny Schmidt, a University of Minnesota chemical engineer.

Energy Secretary Samuel Bodman pegged the current cost of gasification as being about twice as much as the average $1.10 per gallon cost at corn-based ethanol plants.

A gasifier turns plant material into a synthesis gas consisting mostly of carbon monoxide and hydrogen. The "syngas" then could be turned into a variety of fuels including ethanol, hydrogen and environmentally friendly versions of diesel or gasoline, Schmidt said.

"These gasifiers are some high-tech stuff with high pressures and some more complexities," he said. "But they're probably more versatile at the end of the day to modify them as the demand and supplies change."

Gasification is a fairly simple process, based on chemistry developed in the 1920s, said Robert Brown, an Iowa State University chemical engineering professor and director of the school's Office of Biorenewables Programs.

The syngas produced during gasification mixes more readily with chemical catalysts, so it could be more easily turned into other fuels, chemicals and materials. Just add steam and you could produce hydrogen to power a fuel-cell vehicle, Brown said.

Of the six companies awarded U.S. Department of Energy grants, three will use versions of fermentation technology. But two others will use gasification and one will use a hybrid of both technologies:

• Alico Inc., a LaBelle, Fla.-based agribusiness company, would get up to $33 million to turn yard waste, wood waste and citrus peel into syngas, which would then be converted into ethanol, electricity and hydrogen.

• Range Fuels Inc., of Broomfield, Colo., would get up to $76 million for a plant near Soperton, Ga., to convert timber scraps into syngas to make ethanol and methanol.

• Abengoa Bioenergy, a St. Louis-based division of Spain's Abengoa SA, would receive up to $76 million for an 11.4 million gallons-per-year plant in Colwich, Kan., that would use both biochemical and thermochemical processes to convert corn stalks, wheat straw and switchgrass.

The Energy Department helped demonstrate the viability of gasification in the mid-1990s when it awarded Georgia-based FERCO $9.2 million to help build a power plant running on wood chips. By 2001, the $18 million plant in Burlington, Vt., was generating more than 200 megawatt-hours of electricity a day.

To compete in the marketplace, companies will have to make sure their feedstock supplies are consistent, do more research into catalysts that turn syngas into fuels, and develop better materials to contain the thermochemical reactions, according to the Energy Department.

The syngas would have to be cleaned and conditioned to remove contaminants, which is an expensive task. Energy officials say companies will have to bring down those costs if they're to compete in the market.

Mark Paster, a U.S. Department of Energy technology development manager who's studying ways to turn biomass into hydrogen, said both fermentation and gasification "are very viable and both routes continue to be researched and developed."

Paster said biomass helps reduce greenhouse gasses, so any method that can reach commercial viability will be better than one based on fossil fuel.

"There may not be a single winner, just like there's no winner in how we produce electricity," he said. "We do it in a variety of ways."


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1 posted on 03/04/2007 5:03:14 PM PST by nypokerface
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To: nypokerface

ethanol is nearly as big a hoax as global warming


2 posted on 03/04/2007 5:05:57 PM PST by xcamel (Press to Test, Release to Detonate)
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To: nypokerface

For later


3 posted on 03/04/2007 5:06:44 PM PST by redgolum ("God is dead" -- Nietzsche. "Nietzsche is dead" -- God.)
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To: nypokerface

Are they referring to the Fischer-Tropsch method here?


4 posted on 03/04/2007 5:08:23 PM PST by RegulatorCountry
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To: xcamel

Are we really going to grind up all the trees to fuel our cars ?


5 posted on 03/04/2007 5:09:11 PM PST by Eric in the Ozarks (BTUs are my Beat.)
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To: Eric in the Ozarks

trees, grass, corn, beets, cats, cows..


6 posted on 03/04/2007 5:11:58 PM PST by xcamel (Press to Test, Release to Detonate)
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To: RegulatorCountry
Are they referring to the Fischer-Tropsch method here?

No.
7 posted on 03/04/2007 5:14:54 PM PST by SpaceBar
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To: xcamel

trees, grass, corn, beets, cats, cows, kudzu?


8 posted on 03/04/2007 5:15:50 PM PST by Not now, Not ever! (The devil made me do it!,.......................................................( well, not really.)
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To: xcamel

Nonsense!

My dad works with the technology. It is not a hoax and I suggest that you do some research.


9 posted on 03/04/2007 5:17:11 PM PST by clueless123 (Colt Revolvers - The Worlds Right Arm)
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To: clueless123

Your nickname speaks volumes.


10 posted on 03/04/2007 5:19:00 PM PST by xcamel (Press to Test, Release to Detonate)
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To: xcamel

How about butanol?

www.butanol.com


11 posted on 03/04/2007 5:19:48 PM PST by RazzPutin ("You have told us more than you can possibly know." -- Niels Bohr)
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To: RazzPutin

butanol works better, but runs afoul of the VOC laws.
(big smog maker)


12 posted on 03/04/2007 5:21:59 PM PST by xcamel (Press to Test, Release to Detonate)
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To: RegulatorCountry

I think it's the Taco Bueno solution that they're working on.


13 posted on 03/04/2007 5:22:50 PM PST by true_blue_texican (...against all enemies, foreign and domestic...)
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To: nypokerface

Gassification is proven technology.

Once syngas is made, it can be turned into anything that the current petrochemical industry produces using off the shelf petrochemical technology.

I would hate to see them waste the gas making ethanol when they can make a superior product, diesel!"


14 posted on 03/04/2007 5:27:43 PM PST by dangerdoc (dangerdoc (not actually dangerous any more))
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To: SpaceBar

Well, what other gasification methods date to the 1920's?


15 posted on 03/04/2007 5:32:07 PM PST by RegulatorCountry
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To: true_blue_texican

"I think it's the Taco Bueno solution that they're working on."

Methane, lol?


16 posted on 03/04/2007 5:33:26 PM PST by RegulatorCountry
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To: clueless123; xcamel

"My dad works with the technology. It is not a hoax and I suggest that you do some research."

Ok, it's not a hoax. It's a boondoggle. One to reward campaign donors and buy votes in ethanol producing states.


17 posted on 03/04/2007 5:36:11 PM PST by flashbunny (<--- Free Anti-Rino graphics! See Rudy the Rino get exposed as a liberal with his own words!)
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To: nypokerface
"For corn-based ethanol plants, the process of producing ethanol is as simple as brewing beer...."

Brewing beer or wine might be simple -- brewing drinkable beer or wine is not.
18 posted on 03/04/2007 5:38:18 PM PST by USFRIENDINVICTORIA
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To: nypokerface
The term"syngas" caught my eye. I read an article in Popular Science about a technology called "Plasma Converters" that was fed with ordinary garbage. It actually breaks down garbage into elemental forms with electrical plasma. The byproducts are hydrogen and carbon monoxide...syngas. The thing is, once it starts it's self sustaining as long as you keep feeding it garbage because the heat from the process is routed to exchangers that heats steam to power turbine generators

The Prophet of Garbage:
Joseph Longo's Plasma Converter turns our most vile and toxic trash
into clean energy—and promises to make a relic of the landfill




19 posted on 03/04/2007 5:40:58 PM PST by BlueOneGolf (The 2nd Amendment...America's ORIGINAL Homeland Security! http://www.ar15.com)
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To: true_blue_texican

Too many burritos and I too experience gassification.

Harness the explosive power of methane and the discovery of atomic energy will pale into insignificance.

Imagine unidimensionally focused channeling of the campfire scene from "Blazing Saddles".

The Iraqi Supergun!


20 posted on 03/04/2007 5:41:33 PM PST by elcid1970
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