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To: Right Wing Professor; Alamo-Girl; betty boop
"The Gibbs free energy is just -T times the entropy change, at constant pressure. It's just a proxy for the total entropy."

Since I mentioned reactions I thought it was clear, but...

delG = delH -T*delS

The enthalpy, or heat of reaction is larger than T*delS and what drives "the signal".

1,893 posted on 02/08/2005 7:28:51 AM PST by spunkets
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To: spunkets

Sufficient delH also can reduce S...


1,894 posted on 02/08/2005 7:38:34 AM PST by spunkets
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To: spunkets
delG = delH -T*delS

S in that equation is the system entropy. There is also the entropy of the surroundings. The entropy change in the surroundings is -qrev/T, and since the reversible heat at constant pressure equals the enthalpy change Delta H, DeltaH = -T DeltaSsurr. So DeltaG = -T(Ssurr+Ssys)

1,896 posted on 02/08/2005 7:54:01 AM PST by Right Wing Professor (Evolve or die!)
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