The relationship between entropy and probability is S=k ln W (Boltzmann's equation). W is the number of possibilities; in the case of your coin, W = 250
The chemisty -- the ionic attraction -- reduces the number of available states, or rather makes some states more likely then others. The effect is to greatly reduce W or what would simply in some entropy model to W. Again, I'm assuming you are talking about the crystal being formed out of aqueous solution.