The use of PO Box 34567 for Ashland Chemical was previously noted on this thread, and dates from 1991.
I looked it up on the USPS zip code finder page, and PO Box 34567 does NOT exist today. The address standardized to PO Box 24567, zip code 77229.
Strange indeed...
There are links to other docs in this thread that have official letterhead for the unit, and they show the 34567 PO Box.
I guess they just wanted something easy to remember.