Sure, but your argument seemed to have been that the do-not-call list would give bureaucrats the power to determine who qualifies as a charity or a polital organization. I'm saying that's a totally separate determination that has nothing to do with the DNC list.
Back when I still had a land line phone I got calls from "charities" offering to help with my debt payments.
That might be a problem with the rules on non-profits, but it has nothing to do with the DNC list.