Or this: these individuals can INDULGE sexual attractions of varying sorts. And even your use of the word "develop" indicate a chioce.
Of course, what is needed is a lot of hard biological research results. Whenever cadavers are available for autopsy and tissue examination, do analysis of brain structure.
First of all, there's no guarantee that looking at a dead preserved brain will shed light on the behavior and choices of the person who used to inhabit the body. Second, even if all kinds of people who used to practice same sex acts do have some kind of brain difference (which is highly unlikely) there is every chance that the brain difference could have been CAUSED by their same sex behavior.