He proposed to Catwoman just last year.
Superman has Lois Lane, but they dont go beyond looking into each others eyes
Superman married Lois in 1996, and they have a son who is 10 years old.
Peter Parker and Spiderman like Mary Jane, but they are usually too shy/awkward to do much about that attraction.
They were married in 1987.
To put it mildly, I may not have kept up with comics since the 1960s.