Probably Susan Rice.
Bingo!
Susan Rice used her own name. Whoever did it did not have credentials but believed himself free to use Powers. Thats why I say Obama.
It includes
Barak Obama
Susan Rice
Ben Rhodes
Valerie Jarrett
Maybe a few more
At DIA it would have been Clapper and at CIA it would have been Brannen
In the FBI it could have been Comey, McCabe , Strzok or Bill Priestap
“Probably Susan Rice.”
As National Security Advisor, Rice would have been even more authorized to unmask, and did. She may have wanted more credited to Power, and as former UN Ambassador would have known how to work around that system using POwer’s credentials.
Another possibility would be Valerie Jarrett. Not sure if her position afforded her the same level of security clearance the others had.