I searched Wikipedia on U236. It does support fission and won’t go boom, but it appears as a trace isotope in minimal quantiles, but comes from enriching U238 (natural) into U235 becoming a waste product.
You take U238 turn it into a gas at like 7000 degrees F then by spinning it in centrifuges the force from spinning separates the atoms and U238 is denser than U235.
I'm actually very familiar with centrifuge and other types of Uranium enrichment.