Hmmmm. I think I can guess why she wasn't given a breathalyzer.
I assume "allowed" means other cops on the scene interviewed them and then let them go.
I'm not sure why someone else called 911, maybe there were other cars on the road and someone else called while the police officer was checking on his wife to make sure she was OK. It seems though he might have called it in (have no idea whether off-duty canadian police have police radios with them).