sodium fluoride is regularly added to water by water treatment plants. it is still used. it is also the type used in all major toothpaste brands.
I worked on Crest toothpaste at P&G at the time of the ADA endorsement. The active ingredient in Crest was originally stannous fluoride, rather than sodium fluoride.
I can attest to the validity of the clinical tests which revealed 30-50% reductions in the incidence of caries. Indeed, since Crest's introduction, childhood caries problems have essentially been wiped out. A huge step forward in public health...
Sodium silicate is also added regularly to water supplies... Somethings are added in some places that are not added in others...
I’m generally suspicious of anything added to the water... I don’t know who is adding things, when, where or how much... some water in California smells like a swimming pool...
Some of the idiots working for water companies or public water utilities couldn’t measure a gallon accurately, let alone calculate molar volumes and empirical formulas.