For the natural contributions the estimates are more difficult. The ocean cycle is about 50 Gt per year in both directions, see www.opl.ucsb.edu/tommy/pubs/hawaii01/bishop.pdf (A petagram is the same a a gigatonne) Vegetation takes up 150-175 Gt of carbon per year mostly in the northern hemisphere spring. They release most of that in the fall. See http://wattsupwiththat.com/2011/09/29/plants-gobbling-up-co2-45-more-than-thought/ The total ratio (ocean plus land vegetation) is about 30 to 1, but it's very rough.