That only happens when they attempt to violate Gresham’s Law.
“Bad money pushes out good money.” when there are two currencies of different value, people spend the one worth less and save the one worth more.
That is, you get such things when you have two currencies of different values, which is why in this case you have a controlled exchange rate.
At first, Greeks would want Euros instead of Drachmas. But Euros would have limited value in Greece, since they could not be exchanged at banks, nor used by major retail stores. But outside of Greece, a Euro would just be a Euro, and a Greek who bought a lot of goods outside of Greece and wanted to bring it back in would be halted by ordinary customs controls.
And Drachmas would be worthless outside of Greece, unless exchanged for Euros at the going rate.
And all the while, mind you, there would be efforts to create parity of the two currencies.
This is also where it matters that Euros are a fiat currency, but Drachmas would be a reserve currency. This would tend to make Drachmas worth *more* than Euros.
Certainly there would be some black market, but the effort is to make the profit margin for such activities so small that it’s not worth it.
I was in Greece last year but managed to avoid the riots. It could be a lot worse this year--I don't think I would want to visit the country. Tourists from other countries may be wondering how safe it will be. Maybe it will be OK in the small towns.