If the chief clown accepts the UN chair position, he will be in direct violation of Article 9 of the US Constitution.
I assume you refer to Clause 8 of Article 9?
Clause 8: No Title of Nobility shall be granted by the United States: And no Person holding any Office of Profit or Trust under them, shall, without the Consent of the Congress, accept of any present, Emolument, Office, or Title, of any kind whatever, from any King, Prince, or foreign State.