Based on a digested compendium of what I've read, it's fairly clear that corn ethanol doesn't gain much in CO2 "savings". Biomass and cellulosic ethanol should, if the digestion process can become large-scale. So I think it depends on the source.
But large-scale production from algal ponds might be the most efficient.
You could use captured CO2 from power plant emissions to force-feed the algae. As I understand it, there is already at least one prototype CO2 scrubber out there. :-)