No, not directly. Although the employer is going to have to learn to be more flexible or move locations if they start losing employees because traveling to work becomes cost prohibitive.
It isn't as simple as just raising toll prices until people find a way to either drive less or companies relocate. It also isn't good for your tax base if you drive out companies.
However, the costs of maintaining roads has been going up, and the gas taxes have remained a constant number of cents per gallon rather than rising with inflation. Something does have to change.
We "have" to go to toll roads as we go to electric cars because it is too difficult to tax your home electric bill to pay for the roads.
What REALLY needs to be done is to put a couple of thousand dollar "lump payment" road tax on electric car license fees every year (gas burning cars pay it over time at the pump).
If I have to pay gas tax AND toll tax, I should get a tax rebate or lower toll fee. It is double taxation.