Dr. Willard Libby, the founder of the carbon-14 dating method, assumed this ratio to be constant. His reasoning was based on a belief in evolution, which assumes the earth must be billions of years old. Assumptions in the scientific community are extremely important. If the starting assumption is false, all the calculations based on that assumption might be correct but still give a wrong conclusion. In Dr. Libby’s original work, he noted that the atmosphere did not appear to be in equilibrium. This was a troubling idea for Dr. Libby since he believed the world was billions of years old and enough time had passed to achieve equilibrium. Dr. Libby’s calculations showed that if the earth started with no 14C in the atmosphere, it would take up to 30,000 years to build up to a steady state (equilibrium).
If the cosmic radiation has remained at its present intensity for 20,000 or 30,000 years, and if the carbon reservoir has not changed appreciably in this time, then there exists at the present time a complete balance between the rate of disintegration of radiocarbon atoms and the rate of assimilation of new radiocarbon atoms for all material in the life-cycle.
2Dr. Libby chose to ignore this discrepancy (nonequilibrium state), and he attributed it to experimental error. However, the discrepancy has turned out to be very real. The ratio of 14C /12C is not constant.
The Specific Production Rate (SPR) of C-14 is known to be 18.8 atoms per gram of total carbon per minute. The Specific Decay Rate (SDR) is known to be only 16.1 disintegrations per gram per minute.
3 What does this mean? If it takes about 30,000 years to reach equilibrium and 14C is still out of equilibrium, then maybe the earth is not very old.