Even if it is totally green, the more green energy he uses, the less there is for others to use, requiring more CO2 producing electricity to supply the rest of us folks.
As long as "green electricity" is a limited amount, then cO2 producing electricity must make up the rest. So less energy use, whether green or not, will decrease the total CO2 output.
(not that I am a global warming advocate, just pointing out the hole in Gore's argument)