From what I remember from a show on ISS construction, I think copper was the choice for tools,
since it could withstand the cold and maintain many of the properties. That is, not become overly
brittle while still being hard.
I have no idea as to fasteners, pipes, trusses, etc.
Station tools are primarily aluminum and stanless steel. Copper/brass and some plastics also are used, depending on operational needs for mechanisms.