FEMA's web site says it started working with the LA National Guard on 8/28 to coordinate a response.
The Louisiana Governor had control over HER guard. Calling in other states' guards must be done by a formal request to the President, which hadn't happened until Thursday.
I believe that, and there was a NG presence before the hurricane hit, checking people into the SuperDome.
The amount and deployment of NG resources is first the governor's prerogative still - and not the President's.