The areas where they are losing foam are in the cryogenic repressurization lines which means they are dealing with ambient temperatures on the external side and negative freezing temps only inches away behind the tunnel covers.
I'm not a rocket scientist, I'm a carpenter drinking beer (LOL) but I think I know what I am talking about.
That is just the purpose of the freon from my reading. It improves adhesion of the foam to this type of surface, and within itself.
I also use polyurethane foam; have 2.5 inches of it on my roof, for one thing (minimally expanding). No problem getting it to adhere there. As you suggest, removing it is more of a problem in construction than application. However, I can easily pull it off the edges of the roof after weathering for five years now, but this is the area that wasn't protected by an epoxy overcoat.