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I dried and ground some habaneros, in the kitchen, I didn't
touch them had rubber gloves on. burnt my eyelids and face,
major heat.
2nd time put a plastic bag over the grinder, same thing, got
burnt even tho i let the powder sit before bottling.
3rd time put the plastic bag over my head, worked ok, except
they need to be bottled outdoors preferably not down wind.
my cousin calls them peppers from hell.

Problem here is dust from the dried peppers. You can avoid the problem you describe by NOT drying the habs first; mince them undried in a closed canister food processor (e.g. Cuisinart), with whatever other chiles and other ingredients you fancy, and there you go. If you want to dry the mixture later -- in the oven, say -- spread it out on a cookie sheet and cover loosely with foil while drying. Dust thus produced will be minimal.

If your skin is more sensitive than most folks' to capsaicin, rub a mixture of skin cream and butter or vegetable oil on the exposed areas before preparation. Capsaicin is readily soluble in fats and vegetable oils, and this mixture will quite literally insulate you. If your eyes are a problem, any cheap pair of sports goggles will work; just be sure to tape over the little air vents at the side.

Plastic bags over the head? Sounds pretty kinky to me...(g!)