American History Museum
Museum of Natural History
National Air & Space Museum (& Dulles Annex!)
NRA National Firearms Museum (Fairfax)
Arlington National Cemetary
Lincoln, Jefferson, Washington Monuments
Vietnam, Korean War, Iwo Jima (USMC) Memorials
Mount Vernon
International Spy Museum
Holocaust Museum
Take the Metro and TourMobile for downtown DC - way easier than walking and parking. Keep in mind all the downtown museums have metal detectors and security inspections.
The Manassas Battlefield is usually very quiet, and has a first class Visitors Center.