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Capsized barge in Texas port, may explode
Fox News Channel | November 6, 2003

Posted on 11/06/2003 12:31:45 PM PST by Tree of Liberty

Just caught the tail end of the report. Apparently, there is a capsized barge in a Texas port (didn't get the port's name). According to the Coast Guard, there are chemicals on board that, if mixed, will detonate.


TOPICS: Breaking News; News/Current Events; US: Texas
KEYWORDS: port; texas
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To: spunkets
If the barge had been loaded with drums of acid and loaded that way, I could understand it, but the pictures and descriptions indicate that this was just one big floating tank. I don't know how you could get the 235,000 gallons loaded unevenly.

But something obviously made it flip over, and it certainly wasn't wind or water action.

41 posted on 11/06/2003 4:17:16 PM PST by Dog Gone
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To: spunkets
So what kind of suit will the divers wear that won't be eaten by the acid...
42 posted on 11/06/2003 4:17:25 PM PST by tubebender (FReeRepublic...How bad have you got it...)
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To: 76834
I was in high school in Houston at the time of the first explosion. They asked for anyone with first aid training. I went to Texas City for a while. We were sent home before the second explosion. Lucky I guess. I had friends injured in the second explosion. Later when I was in the Coast Guard we had a lot of lectures and discussion about how they identified remains.
43 posted on 11/06/2003 4:19:19 PM PST by FreePaul
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To: tubebender
rubber, of course.
44 posted on 11/06/2003 4:22:36 PM PST by oyez (blank)
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To: FreePaul
What an experience!Glad you are here to tell about it!A lot was learned from that terrible sequence of events.
45 posted on 11/06/2003 4:23:40 PM PST by MEG33
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To: FreePaul

46 posted on 11/06/2003 4:25:42 PM PST by deport
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To: Dog Gone
I doubt there is a barge built to contain concentrated sulfuric acid that is not comparmentalized. Whether the compartments are containers made to fit, or integral compartments, they have to be lined so they don't disolve. Stainless tanks are probably what are in the hold. They wouldn't make the whole barge out of stainless. It would cost too much.
47 posted on 11/06/2003 4:27:50 PM PST by spunkets
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To: tubebender
Rubber.
48 posted on 11/06/2003 4:28:36 PM PST by spunkets
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To: sam_paine
Big deal. Texas City is always on fire.

If I posted every explosion, fire and leak in the heavily industrial areas like Texas City and Pasadena, Jim would need a bigger server.

49 posted on 11/06/2003 4:33:18 PM PST by TexasCajun
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To: deport
Overturned barge declared unsafe by Coast Guard
Updated: 11/6/2003 4:06 PM
By: News 24 Houston web staff

A barge transporting 235,000 gallons of sulfuric acid in the Texas City harbor capsized Monday, and early Wednesday morning it flipped on its side.

That barge has now become unsafe, according to the U.S. Coast Guard.

A chemical reaction has been occurring since the barge turned over and that has been causing the barge to heat up.

A safety zone had already been established around the barge.
Water is being sprayed on the barge to disperse any possible chemical vapor release.

Workers from nearby plants, such as Sterling Chemicals, are being evacuated as a precaution according to the Coast Guard. No homes are impacted by the situation, according to the Texas City Office of Emergency Management.

The city is monitoring the situation, but have not called for a shelter in place.

The school district is meeting with Emergency Management Coordinator Bruce Clawson at this hour, but at this time there are no calls for lockdown. There are no schools in the immediate area of the leak.

The school district has restricted outside activities, bringing the kids back inside from recess and other outdoor activities.


http://www.news24houston.com/content/top_stories/default.asp?ArID=18219

50 posted on 11/06/2003 4:37:07 PM PST by deport
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To: deport

Capsized Barge Leaks Sulfuric Acid

Chemical Workers Evacuate

POSTED: 11:17 a.m. CST November 6, 2003
UPDATED: 5:52 p.m. CST November 6, 2003

A leaking, capsized barge forced an evacuation around the Texas City Harbor Thursday afternoon after officials worried about a possible explosion, News2Houston reported.

Crews with the Environmental Protection Agency, the National Oceanic Atmospheric Administration and the Coast Guard were trying to upright the vessel, which carried 235,000 gallons of sulfuric acid when it capsized Monday night.

During the cleanup process, the sulfuric acid had a chemical reaction with water, causing a bulge to form from a buildup of hydrogen gas.

Chemical companies within a half-mile radius of the barge, as well as emergency responders, were evacuated as a precaution.

Officials are using fire hoses to spray water on the barge.

"The water (being sprayed) on the barge is not actually to cool the barge down, but it's to prevent any gasses that might escape from going anywhere. It's a safety barrier," Coast Guard Chief Warrant Officer Adam Wine said. "At this time, there has been no reading or indication of any toxic fumes coming from the barge. We noticed a rise in temperature and a little buckling on the barge. You could actually hear a pinging of metal similar to your water tank heating up."

Officials said there's a minimal threat of an explosion.

"We have all monitoring equipment (at the barge). We have infrared cameras so that tells us how much heat is there. There's that potential threat but there's not any indication that it's immediate," Wine said.

"We're not anticipating any kind of explosion, but we've taken precautions to have at least a 100 meter distance around the barge," said Richard Kaser, port captain.

Kaser said that crews are expected to work through the night to alleviate the pressure in the barge.

"I feel very confident that the situation is under control and that we'll have all those resolved in the very near future," he said.

Capsized Barge In Texas City Harbor

The Texas City Independent School District kept its students indoors. No schools are within the immediate area of the barge.

Authorities are monitoring air and water quality.

The public is not in danger, officials said.

"As it stands right now, they should continue their lives as normal. That's our message for our citizens today," said B.C. Clawson, with Texas City Emergency Management.

The barge is in a commercial area, so no recreational or fishing boats were affected.

The Coast Guard Marine Safety Unit in Galveston is investigating the cause of the accident.

The barge was operated by Martin Product Sales LLC of Kilgore

VIDEO of Bardge at this link

51 posted on 11/06/2003 4:47:41 PM PST by deport
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To: spunkets
Hmmm, so some moron probably decided to fill compartments on one side of the barge without bothering to balance the load, in all likelihood.

That's the only explanation that makes sense. This happened right at the Sterling chemical plant, which fits in with it being a loading mistake.

52 posted on 11/06/2003 4:48:15 PM PST by Dog Gone
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To: CWOJackson
Chief, a CWO is a part of the video in the link in #51.....
53 posted on 11/06/2003 4:50:09 PM PST by deport
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To: deport
Alright. He's an eng-gin-neer from the local Marine Safety Office.

I was involved in a similar situation off of Cape Hatteras only the barge was loaded with Oleum (concentrated sulphuric acid). That barge did capsize and according to the crew of the tug danced about six feet off the water as the cargo hit the water.

When we got it righted the top look like it had been near a nuclear blast. I still have photos of it (somewhere).

This is the kind of thing I DO NOT miss.

Thanks for the ping.

54 posted on 11/06/2003 4:57:41 PM PST by CWOJackson
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To: Dog Gone; spunkets
I would expect that there are divided compartments or at least baffles that section it off in some way.

There is a thing called "free surface" that is very dangerous on ships. It is the cause of many capsizings. Free surface is whenever you have a half-full tank of any liquid. A tiny shift in the vessel can cause it to basically "slosh" from side to side. Even a little bit can generate an enormous force... even only a couple of inches of wave inside a large tank and it can be many many tons of liquid moving from side to side.

This is why fuel and water tanks are safer if they are fairly small, and then interconnected with other small tanks. Less free surface effect than a single large tank.

This free surface would be a monumental problem if the barge were just one big open tank. Even with baffles or compartments it would still have to be loaded very carefully, and I would think that it would be pretty easy to foul up.
55 posted on 11/06/2003 5:08:46 PM PST by Ramius
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To: deport
I'm not sure I like seeing that tank farm right nearby. Any word on what's in those big shoreside tanks?
56 posted on 11/06/2003 5:10:15 PM PST by Ramius
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To: Dog Gone
The barge is like a large shallow roasting pan. If it contained noncorrosive matl's, it would have to have baffles like an ice cube tray to avoid tipping. In this case they probably have full compartments. I don't know how they might be connected. Yes, the folks loading it were morons. The barge apparently flipped completely upside down then the acid leaked into the barge itself. After that the acid began to dissolve the inside of the barge and gas was evolved. By yesterday the pressure had caused a bulge which caused it to turn on it's side. The above pics show it. It looks like a section of dock floating in the water. It looks full. There's not much sticking out of the water.

Sulfuric acid is almost twice as dense as water. The spilled acid inside has a lot of room now to swish around. That explains it's turning on it's side after developing the bulge. A small amount of distortion results in a large weight transfer.

57 posted on 11/06/2003 5:11:16 PM PST by spunkets
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To: Ramius
"Any word on what's in those big shoreside tanks?"

Probably sulfuric acid.

58 posted on 11/06/2003 5:14:11 PM PST by spunkets
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To: Ramius
Any word on what's in those big shoreside tanks?


No Idea and I've not read anything that gives any indications.... The two smaller white tanks in the center/top of the picture appear to be empty or at least not completely full as their tops are down inside the tank wall... The large one next to the crane, who knows.....
59 posted on 11/06/2003 5:20:08 PM PST by deport
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To: spunkets
The Sterling Chemical plant where this took place also produces styrene, acrylonitrile, acetic acid, plasticizers, sodium cyanide and disodium iminodiacetic acid (DSIDA). If this was their only loading facility, I suppose those tanks might contain just about anything.

And don't ask me what disodium iminodiacetic acid is. I haven't a clue.

60 posted on 11/06/2003 5:40:25 PM PST by Dog Gone
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