Rand Paul voted Yes.
The below linked article contained the following wuote:
Sen. Rand Paul, R-Ky., was the lone member of his party to vote against his confirmation.
Fox News also has Prima Donna voting nay:
“Kansas Rep. Mike Pompeo was confirmed as CIA Director by a 66-32 vote, the closest of three Senate votes on Trump appointments. Thirty Democrats, along with Sen. Bernie Sanders, I-Vt. and Sen. Rand Paul, R-Ky., opposed Pompeo, variously citing his positions on key issues like surveillance, torture and Russia’s meddling in the 2016 election campaign.”
Looks like there's some fake news flying around the interwebs.