The reason for no convictions of southern leaders being: (1) the National government did not want to exacerbate the hot feelings; (2) a court ruled that it was the states not the individuals that levied war(A Virginia Federal District Court if I remember correctly.)
The 10th amendment could be construed as meaning that the states had a right to secede. I suspect that most of the men who voted in the state ratifying conventions assumed that secession was a potential option. After all, they were voting to secede from an existing arrangement, the Articles of Confederation.