Popper wasn't a skeptic, he was a philosophical realist. And we indeed cannot have certainty (in the straightforward sense of the term) in ANY claim about the natural world because our information is ALWAYS incomplete and there is ALWAYS the possiblity that new facts or knowledge will undermine our previous claims.
This is NOT skepticism. It does NOT mean that our knowledge of the natural world is not good, or valid, or useful, or anything of the like. All it means is that our knowledge is always subject to improvement or revision.
Of course it is. Denying that anything can be proven is even more than the definition of skeptic requires:
skep·tic also scep·tic ( P ) Pronunciation Key (skptk) n.
1. One who instinctively or habitually doubts, questions, or disagrees with assertions or generally accepted conclusions.
BTW - you cannot say that evolution is a proven fact and also say that nothing can be proven.