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Grad student discovers unique valleytronics properties of tungsten disulfide monolayer film
phys.org ^ | December 3, 2015 | Denis Paiste & Provided by: Massachusetts Institute of Technology

Posted on 12/03/2015 2:11:31 PM PST by Red Badger

Researchers at the Gedik Lab at MIT use strong ultrafast laser pulses to stimulate changes in material, followed by a weaker probe laser pulse after some time delay to monitor the changes with femtosecond time resolution. Tungsten (W) atoms are black, and sulfur (S) atoms are yellow. Credit: Edbert Jarvis Sie

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Monolayer films of tungsten disulfide, just three atoms thick, have unique electronic valleys which can be manipulated with laser light. This finding, by MIT physics graduate student Edbert Jarvis Sie, Associate Professor Nuh Gedik, and colleagues, was significant enough to warrant placement on the cover of Nature Materials earlier this year.

The cover illustrates a tornado-like whorl of light, lifting an electronic band in the material to a higher energy state, which widens the band gap in the material. This widening is known as the optical Stark effect. The researchers, under senior author Nuh Gedik, the Lawrence C. (1944) and Sarah W. Biedenharn Career Development Associate Professor of Physics at MIT, found that applying circularly polarized laser light lifted the energy in one valley while leaving the energy in the other valley unaffected. "There are two valleys. If we switch the laser polarization, the effect switches to the other valley," Sie says. Gedik spoke about his group's research on topological insulators at the Materials Day Symposium, on Oct. 14, in Kresge Auditorium.

"In materials, electrons travelling in different directions experience different scattering potential with the atoms. This establishes an energy landscape as a function of electron's momentum, which can form a local minimum that we call a valley," Sie explains. "The phenomenon of the valleys only occurs in these extremely thin, monolayer forms of the tungsten sulfur compound, not in its bulk form. These valleys normally have the same energy. But as we apply this circularly polarized light, we can lift the energy of one valley relative to the other."

Seeking chiral edge state

Sie is continuing the research by leading an effort to demonstrate a phenomenon predicted by MIT assistant professor of physics Liang Fu that electrons at the boundary of the laser spot will travel clockwise or counterclockwise depending on their spin and the light polarization, thus creating the so-called chiral edge state. "Research is currently ongoing in order to establish this new phase of matter and to observe it," Sie says. The chiral edge state is predicted to occur in the valley opposite to the one whose bandgap is affected by the circularly polarized light.

MIT physics graduate student Edbert Sie works in the Gedik Lab to innovate optical control of electrons in monolayer materials — and possible new methods for information processing, such as valleytronics. Credit: Denis Paiste/Materials Processing Center ========================================================================================================================================

This valley degree of freedom, or valley index, has a potential to be used for carrying information like in a computer. Transistors nowadays are reaching a fundamental size limit that is either difficult or too expensive to overcome, and monolayer materials like tungsten disulfide may have the capability to carry the next generation of electronics, Sie suggests.

Previous approaches to creating topological insulators involved layering materials such as mercury telluride with cadmium telluride or alloying a material such as thallium bismuth sulfide with an additional element such as selenium, Sie explains. "In our new approach that we are trying to do, we don't need to do any sandwiching or putting additional elements," Sie says. "We take this normal material, a semiconductor, and we just shine light to turn it into a topological insulator."

On-off switch

"By turning on the laser light, we can have a topological insulator; by turning it off, we can have back our semiconductor from the same piece of material. Because this material has a valley index, which is unique, then we can have this sort of valley-flavored topological insulator," he explains.

Sie, 29, who is from Indonesia, is a fifth-year graduate student in physics and expects to graduate in fall 2017. He earned his bachelor's degree in physics at Nanyang Technological University in Singapore. He was a silver medalist in the 2004 International Physics Olympiad, held that year in South Korea. Since his early years, Sie also enjoyed drawing and painting, and earlier considered becoming an artist. That interest came into play when he came up with a sketch for the image that eventually became the cover for his Nature Materials article.

Explore further: Topological insulators: Persuading light to mix it up with matter

More information: Edbert J. Sie et al. Valley-selective optical Stark effect in monolayer WS2, Nature Materials (2014). DOI: 10.1038/nmat4156

Journal reference: Nature Materials


TOPICS: Business/Economy; Computers/Internet; Health/Medicine; Science
KEYWORDS: electronics; memory; tech; tungsten
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1 posted on 12/03/2015 2:11:31 PM PST by Red Badger
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To: ShadowAce

Computer Memory tech Ping!.......................


2 posted on 12/03/2015 2:11:58 PM PST by Red Badger (READ MY LIPS: NO MORE BUSHES!...............)
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To: Red Badger

Whatever! I did this last week. ;)


3 posted on 12/03/2015 2:22:49 PM PST by beaversmom
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To: beaversmom

Well, duh, it seems so obvious!................


4 posted on 12/03/2015 2:23:58 PM PST by Red Badger (READ MY LIPS: NO MORE BUSHES!...............)
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To: Red Badger

Yeah, but does it get him chicks?


5 posted on 12/03/2015 2:24:58 PM PST by Tijeras_Slim
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To: Red Badger
I understood the words "Grad Student Discovers".

After that you lost me.

6 posted on 12/03/2015 2:25:22 PM PST by Lazamataz ( If they try firearm confiscation or gun registration, I go ballistic.)
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To: Lazamataz

It’s basically a possible way to store electronic information, ie, computer memory, that can utilize the properties of a tungsten alloy that would exceed the capabilities of solid state memory using transistors....................


7 posted on 12/03/2015 2:28:00 PM PST by Red Badger (READ MY LIPS: NO MORE BUSHES!...............)
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To: Tijeras_Slim

Yeah, the Big Bang Theory kind............:^)


8 posted on 12/03/2015 2:28:39 PM PST by Red Badger (READ MY LIPS: NO MORE BUSHES!...............)
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To: Red Badger
Sie, 29, who is from Indonesia, is a fifth-year graduate student in physics and expects to graduate in fall 2017. He earned his bachelor's degree in physics at Nanyang Technological University in Singapore. He was a silver medalist in the 2004 International Physics Olympiad, held that year in South Korea. Since his early years, Sie also enjoyed drawing and painting, and earlier considered becoming an artist. That interest came into play when he came up with a sketch for the image that eventually became the cover for his Nature Materials article. Great for him. These are the kinds of immigrants we should encourage. I know this is totally un-pc, and I'm probably committing some kind of crime by saying this, but so often I have seen that Asians' brains are good at math and art. I noticed this throughout school.
9 posted on 12/03/2015 2:29:17 PM PST by beaversmom
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To: Red Badger
Sie, 29, who is from Indonesia, is a fifth-year graduate student in physics and expects to graduate in fall 2017. He earned his bachelor's degree in physics at Nanyang Technological University in Singapore. He was a silver medalist in the 2004 International Physics Olympiad, held that year in South Korea. Since his early years, Sie also enjoyed drawing and painting, and earlier considered becoming an artist. That interest came into play when he came up with a sketch for the image that eventually became the cover for his Nature Materials article.

Great for him. These are the kinds of immigrants we should encourage. I know this is totally un-pc, and I'm probably committing some kind of crime by saying this, but so often I have seen that Asians' brains are good at math and art. I noticed this throughout school.

10 posted on 12/03/2015 2:29:37 PM PST by beaversmom
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To: Red Badger

[[It’s basically a possible way to store electronic information, ie, computer memory, that can utilize the properties of a tungsten alloy that would exceed the capabilities of solid state memory using transistors]]

DANG IT- and here I just went and invested all my life’s savigns into solid state memory- That’ll teach me to jump on hot deals


11 posted on 12/03/2015 2:30:17 PM PST by Bob434
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To: Red Badger; Gamecock; SaveFerris; FredZarguna; PROCON

I knew it was either Tungsten or Wolfram.


12 posted on 12/03/2015 2:31:05 PM PST by Larry Lucido
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To: beaversmom

Ah, so!...............


13 posted on 12/03/2015 2:32:29 PM PST by Red Badger (READ MY LIPS: NO MORE BUSHES!...............)
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To: Red Badger
...optical Stark effect...

"I'll drink to that!"

14 posted on 12/03/2015 2:32:37 PM PST by Alas Babylon! (As we say in the Air Force, "You know you're over the target when you start getting flak!")
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To: Larry Lucido

Now we know why they stopped making incandescent light bulbs!..............


15 posted on 12/03/2015 2:33:14 PM PST by Red Badger (READ MY LIPS: NO MORE BUSHES!...............)
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To: beaversmom

Article says he’s 29. He looks 18!................


16 posted on 12/03/2015 2:33:51 PM PST by Red Badger (READ MY LIPS: NO MORE BUSHES!...............)
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To: Larry Lucido

......or Aluminium..............


17 posted on 12/03/2015 2:35:01 PM PST by Red Badger (READ MY LIPS: NO MORE BUSHES!...............)
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To: beaversmom

Chinese-Indonesian


18 posted on 12/03/2015 2:40:16 PM PST by buwaya
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To: Red Badger

He does look very young. Nice smile.


19 posted on 12/03/2015 2:41:10 PM PST by beaversmom
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To: Red Badger

lol. You same-same as me...un-pc. :)


20 posted on 12/03/2015 2:42:12 PM PST by beaversmom
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