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The Methanol Alternative
The New Atlantis ^ | Summer 2006 | Robert Zubrin

Posted on 02/03/2008 7:18:44 PM PST by Delacon

Any serious energy policy must deal with three critical issues. First, economic: The policy must provide an energy resource base sufficient to allow for continued worldwide economic growth for the foreseeable future. Second, environmental: The policy must be compatible with the long-term flourishing of life on Earth, including human life and civilization. And finally, strategic: The policy must ensure that control of the Earth’s energy resources, and thus its future, lies in the hands of free societies committed to human progress, and taken away from tyrannical and terrorism-promoting states.

George Olah, recipient of the 1994 Nobel Prize in Chemistry, is one of the giants of twentieth-century science, and his coauthors are solid technical men. Together they have written a profoundly important book on energy policy, laying out the basis for a technically achievable approach to all three dimensions of the energy problem.

There is no shortage of energy experts with grand designs and proposals—from technophile dreams of an unworkable “hydrogen economy,” to Malthusian calls for enforced economic limits through conservation, to socialist schemes for creating massive government-subsidized synthetic-fuel industries, to the libertarian faith in the Invisible Hand. Compared to such misguided alternatives, the competence and rationality of The Methanol Economy is refreshing.

The authors begin by describing the dimensions of the worldwide energy problem: Even as our reserves of fossil fuels have grown in recent decades, the demand is growing faster, and as more of the world modernizes, a global energy “crunch” looms. From here, they turn their attention to renewable energy sources and nuclear power, and then they offer a thorough refutation of the technical feasibility of the “hydrogen economy.” This widely-touted panacea cannot work because it takes more energy to produce hydrogen than it yields, because hydrogen is an excessively low-density medium for storing chemical energy, and because an entirely new multi-billion-dollar fuel distribution infrastructure would have to be created to support hydrogen vehicles before any could be sold.

The heart of the book outlines a proposed technical solution to the energy problem. The authors don’t propose new ways of generating energy, arguing that “all feasible alternative and renewable energy sources must be considered and used,” nuclear energy “above all.” Instead, they focus on “the challenges of how to store and best use energy.”

The authors dub their proposal the “methanol economy.” Methanol is commonly known as “wood alcohol” because it can be produced from wood; it can also be made from coal, natural gas, methane hydrates, any type of biomass, or urban waste. It can be used as fuel for internal-combustion engines, and eventually in fuel-cell vehicles. It can also be used as feedstock for producing dimethyl ether, an excellent fuel for non-polluting diesel engines. In short, it is a convenient medium for storing energy and is easily transported and dispensed as a fuel.

Integrating methanol into our energy system would have numerous benefits in the not-so-distant future. As the authors point out, it would make the transportation of liquid natural gas much safer by converting it to less-hazardous liquid methanol before shipping it. Methanol could also be used to produce plastics, synthetic fabrics, and many other non-fuel products currently made from petroleum.

Importantly, methanol can also be produced (in conjunction with an auxiliary electricity source, like nuclear power) by chemically recycling carbon dioxide, which can be found naturally in the air or readily captured from atmosphere-polluting industrial emissions. The methanol produced can, in turn, be used to produce synthetic hydrocarbons and other products now obtained from fossil fuels. If successfully tapped, methanol “has the ability to liberate mankind from its dependence on fossil fuels for transportation and hydrocarbon products,” while reducing the amount of carbon dioxide pumped into the atmosphere.

Consider ethanol as a comparison. The commercial competitiveness of ethanol is somewhat confused by the complex influences of a variety of subsidies and tariffs. By contrast, methanol is currently selling—without any subsidy—for about $0.80/gallon. Given that methanol’s energy content is about half that of gasoline, that price is the equivalent, in energy terms, of gasoline for $1.60/gallon. In other words, we can produce a useful and economically viable vehicle fuel, using a huge domestic and Western hemispheric resource base, at prices lower than gasoline.

So if the economic and strategic questions can be answered, that leaves the matter of methanol and the environment. The authors deal with environmental concerns in a cool, thorough, and methodical fashion. Unlike ethanol, which is edible, methanol is toxic—but so is gasoline. However, unlike gasoline or petroleum, methanol is soluble in water and readily biodegradable by common bacteria, so spills of methanol, whether from defective pumping stations or shipwrecked tankers, would have no long-term environmental impact. Furthermore, as the authors demonstrate, the toxicity of methanol is commonly overstated. In point of fact, methanol is present naturally in fresh fruit, and so low doses of methanol have always been a normal part of the human diet. Unlike gasoline, methanol is not a carcinogen or a mutagen, and the pollutants and other emissions from methanol-powered internal combustion engines are far more benign than emissions from their gasoline-driven counterparts. (Automobile emissions could even be reduced to zero with methanol-based fuel cells.) And if methanol is produced from carbon dioxide or from biomass, its use in place of petroleum acts to counter man-made global warming as well. “Compared to gasoline or diesel fuel,” the authors conclude, “methanol is clearly environmentally much safer and less toxic.”

The book’s greatest shortcoming is in its policy recommendations. It has none. While describing the technological basis for a future world of progress, freedom, economic development, and an acceptable environment, the authors offer no plan for how to make it happen. Given the highly technical and scientific orientation of the authors, this is perhaps understandable, but it is unfortunate.

Indeed, by focusing on the best technical solution without regard to policy implications, the authors sail past essential matters without stopping to seize them. This is most evident on the subject of Flexible Fuel Vehicles (FFVs), automobiles that can operate with gasoline and/or various mixtures of gasoline and alcohol. The most common FFVs in the United States are E85 or M85, meaning that they can function with up to 85 percent ethanol or methanol and 15 percent gasoline. On the subject of FFVs, Olah and his colleagues say:

Although the flexibility of the FFVs represent a powerful means to circumvent the fuel supply conundrum, and also a way to build up the demand for methanol, it must be borne in mind that this is only a compromise.... In the long term, the use of cars optimized to run only on methanol (M100) would be preferable, and would also greatly facilitate the transition to methanol-powered fuel cell vehicles.

Yet without the short term, there is no long term. The authors are correct that, in the abstract, “cars optimized to run only on methanol” would be preferable. But such cars would find no buyers today—because there are no pumps to fuel them, nor will there be, until millions of such cars are on the road. Thus the FFVs, which can run on a combination of gasoline, methanol, and/or ethanol, are not “only a compromise.” Rather, they are the key transitional technology that can make the methanol economy a reality.

Manufacturing a car as an FFV requires only the use of a corrosion-resistant fuel line and a change in the programming of the chip controlling the car’s electronic fuel injector. Thus FFVs can be produced—and currently are being produced in two dozen models, amounting to about 3 percent of total automobile sales in the United States—with essentially no price differential between them and comparable models that only use gasoline. As a result, there is no downside to making flex-fuel capability the standard. If it were required that all new cars sold in the United States had to be FFVs, there would be 50 million automobiles capable of burning methanol on the road in the U.S. within three years. Under such conditions, with methanol producible for a fraction of the cost of gasoline, the methanol pumps would appear soon enough, and the methanol economy envisioned by Olah and his collaborators would soon follow.

But one should not complain too much about the book’s omissions, since it maps out a viable technical approach for addressing our energy problems. They have shown us where to go; now it is time for policymakers to help get us there.


Robert Zubrin, an aerospace engineer, is president of Pioneer Astronautics, a research and development firm.

Robert Zubrin, "The Methanol Alternative," The New Atlantis, Number 13, Summer 2006, pp. 85-88.



TOPICS: Business/Economy; Editorial; Government; Technical
KEYWORDS: georgeolah; hydrogen; methanol
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To: Delacon

bring it on


21 posted on 02/03/2008 7:44:00 PM PST by spanalot (*)
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To: Delacon

I believe methanol is absorbed through the skin much more readily than gasoline and is therefore a greater danger.


22 posted on 02/03/2008 7:45:00 PM PST by Boiler Plate ("Message received, is message sent" Claire Cooper)
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To: Chairman Fred

You have not said one thing to refute the assertions made in this article. I welcome honest criticism but your post contained none.


23 posted on 02/03/2008 7:45:59 PM PST by Delacon (Don't Immanentize the Eschaton.)
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To: Outland

Yet without the short term, there is no long term.

But then again, without the long term, there is only more short term.


24 posted on 02/03/2008 7:47:49 PM PST by Wally_Kalbacken (Seldom right but never in doubt)
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To: crz

“Spent Liquor Gasification.”

Sounds like something I do after a hard night of partying. My wife makes me take it out of the house.


25 posted on 02/03/2008 7:47:54 PM PST by Delacon (Don't Immanentize the Eschaton.)
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To: Boiler Plate

“I believe methanol is absorbed through the skin much more readily than gasoline and is therefore a greater danger.”

Well I don’t want you to bath in it. :)


26 posted on 02/03/2008 7:48:48 PM PST by Delacon (Don't Immanentize the Eschaton.)
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To: Uncledave

post-Superbowl ping


27 posted on 02/03/2008 7:51:11 PM PST by Venerable Bede (www.ronpaulracing.com -- becuase crashing and burning isn't a choice, it's a lifestyle.)
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To: JustaDumbBlonde

Just want to add again that unlike ethanol which is causing food prices to go up, methanol can be made from ANY plant material. That means we can tell the farmers go back to farming food stuffs and get more farmers to grow grass, or wood in areas not suitable to growing grains. Also it can be made by trapping C02 or from methane gas. So no food production problem.


28 posted on 02/03/2008 7:55:17 PM PST by Delacon (Don't Immanentize the Eschaton.)
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To: Delacon; Citizen Tom Paine
If you fill up a gas tank with methanol and let in set it absorbs a lot of water in a week or two.

That surely doesn’t sound technologicly impossible to resolve and cheaply.

That problem is already solved. Modern automobile gas tanks are sealed to the atmosphere when the gas cap is properly secured.

29 posted on 02/03/2008 7:57:06 PM PST by rmh47 (Go Kats! - Got Seven? [NRA Life Member])
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To: Chairman Fred
All of this is the stuff that exits the south end of a north-bound horse.

That's methane, the predominant component of natural gas. That's produced by most critters and people. It's not easy to recover for use as fuel.

Alcohol-based electricity generation represents desperation, not advancement.

The article didn't discuss electricity generation much, if at all, IMHO. The main point was methanol, derived from multiple domestic sources, for a motor vehicle fuel.

30 posted on 02/03/2008 8:03:16 PM PST by neverdem (I have to hope for a brokered GOP Convention. It can't get any worse.)
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To: purpleraine

“I recommend folks read Energy Victory.”

Absolutely. Read this book. No excuses. It will “blow you away” when you realize what it is saying.

What surprised me in reading this book is that ethanol is not the government boondoggle I had been lead to believe.

Actually, I started reading it over the holidays, got about 2/3 of the way through, then dropped it — not because I was bored with it, but just because I moved on to something else. I need to get back to it. And we need to get serious about breaking our dependence on oil for transportation.

Zubrin is quite a character. Several years ago I attended an AIAA dinner meeting in which he spoke about his plan to get humans to Mars within ten years. He is very smart and inspiring. His plan to get to Mars obviously didn’t pan out, but I doubt it was due to any major flaw in his plan. I can only hope his energy ideas receive a better hearing.


31 posted on 02/03/2008 8:04:14 PM PST by RussP
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To: Delacon

“Methanol” sounds speedier than “ethanol”.


32 posted on 02/03/2008 8:05:22 PM PST by Lancey Howard
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To: rmh47

“That problem is already solved. Modern automobile gas tanks are sealed to the atmosphere when the gas cap is properly secured.”

I liked this part:

“Manufacturing a car as an FFV requires only the use of a corrosion-resistant fuel line and a change in the programming of the chip controlling the car’s electronic fuel injector. Thus FFVs can be produced—and currently are being produced in two dozen models, amounting to about 3 percent of total automobile sales in the United States—with essentially no price differential between them and comparable models that only use gasoline. As a result, there is no downside to making flex-fuel capability the standard. If it were required that all new cars sold in the United States had to be FFVs, there would be 50 million automobiles capable of burning methanol on the road in the U.S. within three years. Under such conditions, with methanol producible for a fraction of the cost of gasoline, the methanol pumps would appear soon enough, and the methanol economy envisioned by Olah and his collaborators would soon follow.”


33 posted on 02/03/2008 8:05:41 PM PST by Delacon (Don't Immanentize the Eschaton.)
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To: Boiler Plate
I believe methanol is absorbed through the skin much more readily than gasoline and is therefore a greater danger.

Who is taking a bath in it? If there is a large accidental exposure, all you need is water.

34 posted on 02/03/2008 8:06:22 PM PST by neverdem (I have to hope for a brokered GOP Convention. It can't get any worse.)
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To: Chairman Fred

I think you are missing the point here.

Yes, nuclear power is the answer for electric power, but not for transportation.

And yes, we should be drilling for more oil domestically, but that is only a temporary solution. Ethanol and methanol *combined* with more oil production are the long-term solution.

No science fiction at all. Read the book. Zubrin knows what he is talking about.


35 posted on 02/03/2008 8:08:12 PM PST by RussP
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To: Delacon

If this was as good as the author says we’d already be doing it. There are E85 cars on the road today. What isn’t said is that methanol doesn’t have as much energy as gasoline, so you don’t get as good mileage. Given that a gallon of gasoline now costs $3, then methanol costs ($1.6/67%)=$2.5 and is cost competitive even in a mix with gasoline, but not by a lot.


36 posted on 02/03/2008 8:09:17 PM PST by RKV (He who has the guns makes the rules)
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To: Delacon

Bump


37 posted on 02/03/2008 8:09:42 PM PST by Fiddlstix (Warning! This Is A Subliminal Tagline! Read it at your own risk!(Presented by TagLines R US))
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To: Delacon

I would have been the last to think that a government mandate was the answer, but I think Zubrin is right on this one. Flex-fuel capability costs next to nothing to add on the assembly line, so go ahead and mandate it for new cars. In a few years, when the cost of gasoline goes up even further, gas stations will then have incentive to install ethanol and/or methanol pumps.


38 posted on 02/03/2008 8:15:30 PM PST by RussP
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To: Delacon

“You name any plant matter that we dont eat and it can be used to make methanol unlike ethanol.”

It still has to be grown and harvested on farms that could be producing food.

It seems the advantages of methanol comes from the fact that you could get it from other sources, such as natural gas or via CO2 extracted from the air.


39 posted on 02/03/2008 8:15:49 PM PST by eclecticEel (oh well, Hunter 2012 anyone?)
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To: RKV

Zubrin discusses all this at length in his book. Read it.


40 posted on 02/03/2008 8:16:26 PM PST by RussP
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