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Self-healing rubber bounces back
BBC ^ | 20 Feb 2008 | Roland Pease

Posted on 02/20/2008 6:53:56 PM PST by BGHater


Self-repairing material (Ludwik Leibler)


A material that is able to self-repair even when it is sliced in two has been invented by French researchers.

The as-yet-unnamed material - a form of artificial rubber - is made from vegetable oil and a component of urine.

The substance, described in the journal Nature, produces surfaces when cut that retain a strong chemical attraction to each other.

Pieces of the material join together again as if never parted without the need for glue or a special treatment.

This remarkable property comes from careful engineering of the molecules in the material.

The French researchers are already making kilogramme quantities in their Paris laboratories and say the process is almost completely green, and could be completely so with a few adjustments.

'Tiny hands'

The secret of the substance lies in how the molecules are held together.

A piece of normal rubber, says Dr Ludwik Leibler, who headed the research, is actually a single molecule with billion upon billions of smaller units chemically welded together to form a giant tangled network.

Children are always breaking their toys. Wouldn't it be nice if you could put them back together so easily?


Ludwik Leibler

The elasticity comes from the fact that the strands within the network are buckled like a concertina: pull on them and they straighten and elongate; let go and the buckles reappear.

But break a rubber (or most other solids), and the chemical welds - known as covalent bonds - are also broken.

These cannot be remade. Nor can a piece of rubber be remoulded or reshaped.

"We wanted to see if we could make a rubber-like material using small molecules," Dr Leibler of the Industrial Physics and Chemistry Higher Educational Institution (ESPCI) in Paris told the BBC's Science In Action programme.

The trick was to replace the covalent bonds in rubber with weaker connections known as hydrogen bonds.

These are like hands on neighbouring molecules that can clasp together, but let go when broken.

Dr Leibler quickly realised that this meant not only that the new rubber could be recycled and remoulded many times over, but that if separated by a cut or break, the chemical hands at the fresh surfaces would still be waving about ready to bind again.

Child's play

François Tournilhac, who runs Dr Leibler's laboratories, demonstrated the healing to me.

Using a razor blade he severed a thin strand of the yellowish material (the colour of corn oil), showed me the clean square faces, and then pressed them together.

Almost immediately, the grip was strong enough for him to hold the sample just at one end.

Within an hour the bonds had rebuilt themselves so thoroughly that it was possible to stretch the strand to twice its length without any sign of weakness where the cut had been made.

One obvious use, says Dr Leibler, is for self-healing seals.

Puncture a seal in a compression joint with a nail, and the hole would automatically repair itself.

He also has more playful suggestions.

"Why not use it to make children's toys? Children are always breaking their toys. Wouldn't it be nice if you could put them back together so easily?"

The material was developed with the support of the French company Arkema, which is already investigating whether it can be turned into a commercial product.


TOPICS: Miscellaneous; News/Current Events; Technical
KEYWORDS: flubber; material; rubber
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1 posted on 02/20/2008 6:53:58 PM PST by BGHater
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To: BGHater

Now if you could make a prophylactic out of that stuff....


2 posted on 02/20/2008 6:56:03 PM PST by TheRobb7 (Is the Conservative Movement now just an undertow?)
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To: BGHater
The as-yet-unnamed material - a form of artificial rubber - is made from vegetable oil and a component of urine.

Works good. Smells bad.

3 posted on 02/20/2008 6:56:08 PM PST by ARE SOLE (Agents Ramos and Campean are in prison at this very moment.. (A "Concerned Citizen".)
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To: BGHater

I guess pretty soon, nobody will be able to blame the baby on the torn condom.


4 posted on 02/20/2008 6:56:30 PM PST by squidly
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To: BGHater

French velcro. I’ll pass.


5 posted on 02/20/2008 6:58:44 PM PST by kinoxi
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To: squidly

That is so funny because it is so true.


6 posted on 02/20/2008 6:59:34 PM PST by valkyry1
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To: BGHater

Yeah, but just imagine the mess and bother when your kids store 5 or 6 of these balls together in the same bag....


7 posted on 02/20/2008 7:00:06 PM PST by r9etb
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To: squidly; Xenalyte; Marysecretary; Guenevere; MozartLover
The as-yet-unnamed material - a form of artificial rubber - is made from vegetable oil and a component of urine.

The name is OBVIOUS: Urubber.

Urubber like this and she gets excited.

Urubber like that and she slaps you.

8 posted on 02/20/2008 7:00:14 PM PST by Lazamataz (Why isn’t this in Breaking News????)
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To: BGHater; leda; Gabz

For some wierd reason, this stuff creaps me out.


9 posted on 02/20/2008 7:00:21 PM PST by patton (cuiquam in sua arte credendum)
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To: TheRobb7
Now if you could make a prophylactic out of that stuff....

Maybe clinton would never have been born?

10 posted on 02/20/2008 7:03:05 PM PST by null and void (The less you know, the better Hillary looks.)
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To: patton

Hokey, hokey, hokey, bs, bs, so faked.


11 posted on 02/20/2008 7:03:39 PM PST by american_ranger (Never ever use DirecTV)
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To: EarthBound

The everlast condom- now guaranteed to outlast your perscription of viagra!


12 posted on 02/20/2008 7:06:24 PM PST by MacDorcha ("Anyone but McCain" will work about as well as "Anyone but Bush" (and for the same reasons))
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To: MacDorcha

Lol. It keeps going even if you don’t.


13 posted on 02/20/2008 7:08:32 PM PST by BGHater ($2300 is the limit of your Free Speech.)
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To: TheRobb7

Forget that! I was hoping they could make a car tire where you could fix a flat by pissin’ on it. Like the old guy who asked the doc for just half a Viagra. He didn’t care about his sex life - just wanted to stop peein’ on his shoes.


14 posted on 02/20/2008 7:26:01 PM PST by Emmett McCarthy
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To: ARE SOLE

“Works good. Smells bad.”

You wouldn’t notice that if you were french.


15 posted on 02/20/2008 7:28:03 PM PST by Kirkwood
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To: Kirkwood

Never thought of that ... hmmm. ... you’re right.

Regards


16 posted on 02/20/2008 7:31:57 PM PST by ARE SOLE (Agents Ramos and Campean are in prison at this very moment.. (A "Concerned Citizen".)
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To: BGHater

bmflr


17 posted on 02/20/2008 8:04:19 PM PST by Kevmo (SURFRINAGWIASS : Shut Up RINOs. Free Republic is not a GOP Website. It’s a SOCON Site.)
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To: Cagey; Larry Lucido; MotleyGirl70; Gamecock; jdm; Rb ver. 2.0

Kramer: You know Darren, if you would have told me twenty-five years ago that some day I’d be standing here about to solve the worlds energy problems, I would’ve said you’re crazy… Now let’s push this giant ball of oil out the window.


18 posted on 02/20/2008 8:36:17 PM PST by Mr. Brightside ( Ronald Reagan Would Back McCain - http://www.freerepublic.com/focus/f-news/1970504/posts)
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To: BGHater

component of urine = Urea?


19 posted on 02/20/2008 8:41:24 PM PST by stlnative
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To: BGHater; martin_fierro; aculeus; dighton
The as-yet-unnamed material - a form of artificial rubber - is made from vegetable oil and a component of urine.


20 posted on 02/20/2008 8:50:13 PM PST by Ezekiel
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