Heck, just transfer him from the Roman Rite to the Eastern Rite and its all good! (Would have been more honest if he had figured that out and done it before the wedding though.)
If he is looking for a parish I’m certain his wife will be happy to relocate to Syria with him.
Nope — doesn’t work that way. The Eastern Rites (and the Orthodox) ordain married men, they don’t permit ordained men to marry.