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Why We Don’t Have Battery Breakthroughs
Technology Review ^ | February 10, 2015 | Kevin Bullis

Posted on 02/11/2015 5:10:39 AM PST by thackney

Ectric cars are quick and quiet, with a range more than long enough for most commutes. If you want a car with extremely fast acceleration, the Tesla Model S is hard to beat. And, of course, electric vehicles avoid the pollution associated with conventional cars, including emissions of carbon dioxide from burning gasoline. Yet they account for a tiny fraction of automotive sales, mainly because the batteries that propel them are expensive and need to be recharged frequently.

A better battery could change everything. But while countless breakthroughs have been announced over the last decade, time and again these advances have failed to translate into commercial batteries with anything like the promised improvements in cost and energy storage. Some well-funded startups, most notably A123 Systems, began with bold claims but failed to deliver (see “What Happened to A123?”).

The Powerhouse, a new book by journalist Steve LeVine, chronicles the story behind one of the most dramatic battery announcements of recent years and explains how it came to nothing (see “The Sad Story of the Battery Breakthrough that Proved Too Good to Be True”). The announcement was made in February 2012, at a conference in Washington, D.C., where a crowd of researchers, entrepreneurs, and investors had come to hear the likes of Bill Gates and Bill Clinton expound on the importance of new energy technology—and also to tap into one of the newest funding sources in Washington, the Advanced Research Projects Agency for Energy, or ARPA-E. Founded in 2009, ARPA-E had been tasked with identifying potentially transformational research. The head of that agency, Arun Majumdar, was ready to unveil one of its first major successes: a battery cell, developed by the startup Envia, that could store twice as much energy as a conventional one. The cost of a battery that could take a car from Washington to New York without recharging, Majumdar said, would fall from $30,000 to $15,000. Electric cars would become far more affordable and practical (see “A Big Jump in Battery Capacity”).

Within months, GM licensed the technology and signed an agreement to support its development, gaining the right to use any resulting batteries. The deal was potentially worth hundreds of millions of dollars to Envia, LeVine writes. But soon Envia was getting frustrated messages from GM engineers who couldn’t reproduce the startup’s results. The year after the announcement, the deal was scuttled. Envia’s impressive battery had been a fluke.

LeVine’s account of Envia’s work shows why major progress in batteries is so hard to achieve and why startups that promise world-changing breakthroughs have struggled. Over the last decade we’ve seen remarkable improvements in this industry, but they’ve come largely from established companies steadily making small advances.

Envia’s cell was a new type of lithium-ion battery. Invented in the late 1970s and early 1980s and commercialized in the 1990s, these batteries generate electrical current when lithium ions shuttle between two electrodes. Light but powerful, they have transformed portable electronics. Their use in electric cars, however, is recent. In the 1990s, GM used cheaper lead-acid batteries for its electric EV-1; each battery weighed a bulky 600 kilograms and delivered only 55 to 95 miles before it needed to be recharged. When Tesla Motors introduced one of the first lithium-ion-powered electric cars in 2008, it could go 250 miles on a charge, roughly three times farther than the EV-1. But the vehicle cost over $100,000, in large part because the batteries were so expensive. To cut costs, the lithium-ion-powered electric cars made today by companies such as Nissan and GM use small battery packs with a range of less than 100 miles.LeVine’s account of Envia’s work shows why major progress in batteries is so hard to achieve and why startups that promise world-changing breakthroughs have struggled. Over the last decade we’ve seen remarkable improvements in this industry, but they’ve come largely from established companies steadily making small advances.

Envia’s cell was a new type of lithium-ion battery. Invented in the late 1970s and early 1980s and commercialized in the 1990s, these batteries generate electrical current when lithium ions shuttle between two electrodes. Light but powerful, they have transformed portable electronics. Their use in electric cars, however, is recent. In the 1990s, GM used cheaper lead-acid batteries for its electric EV-1; each battery weighed a bulky 600 kilograms and delivered only 55 to 95 miles before it needed to be recharged. When Tesla Motors introduced one of the first lithium-ion-powered electric cars in 2008, it could go 250 miles on a charge, roughly three times farther than the EV-1. But the vehicle cost over $100,000, in large part because the batteries were so expensive. To cut costs, the lithium-ion-powered electric cars made today by companies such as Nissan and GM use small battery packs with a range of less than 100 miles.

One difficult thing about developing better batteries is that the technology is still poorly understood. Changing one part of a battery—say, by introducing a new electrode—can produce unforeseen problems, some of which can’t be detected without years of testing. To achieve the kinds of advances venture capitalists and ARPA-E look for, Envia incorporated not just one but two experimental electrode materials.

LeVine describes what went wrong. In 2006 Envia had licensed a promising material developed by researchers at Argonne National Laboratory. Subsequently, a major problem was discovered. The problem—which one battery company executive called a “doom factor”—was that over time, the voltage at which the battery operated changed in ways that made it unusable. Argonne researchers investigated the problem and found no ready answer. They didn’t understand the basic chemistry and physics of the material well enough to grasp precisely what was going wrong, let alone fix it, LeVine writes.

With its experimental material for the opposite electrode, this one based on silicon, Envia faced another challenge. Researchers had seemingly solved the major problem with silicon electrodes—their tendency to fall apart. But the solution required impractical manufacturing techniques.

When Envia made its announcement in 2012, it seemed to have figured out how to make both these experimental materials work. It developed a version of the silicon electrode that could be manufactured more cheaply. And through trial and error it had stumbled upon a combination of coatings that stabilized the voltage of the Argonne material. Envia cofounder Sujeet Kumar “understood that the answer was a composite of coatings,” LeVine writes. “But he still didn’t know what the composite was arresting or why it succeeded in doing so.” Since Envia was a startup with limited funds, he “didn’t have the instruments that could figure it out.” But once it became obvious that the results Envia had reported for its battery couldn’t be reproduced, understanding the problem became crucial. Even tiny changes to the composition of a material can have a significant impact on performance, so for all Envia knew, its record-setting battery worked because of a contaminant in a batch of material from one of its suppliers.

The story of Envia stands in sharp contrast to what’s turned out to be the most successful recent effort to cut the price of batteries and improve their performance. This success hasn’t come from a breakthrough but from the close partnership between Tesla Motors and the major battery cell supplier Panasonic. Since 2008, the cost of Tesla’s battery packs has been cut approximately in half, while the storage capacity has increased by about 60 percent. Tesla didn’t attempt to radically change the chemistry or materials in lithium-ion batteries; rather, it made incremental engineering and manufacturing improvements. It also worked closely with Panasonic to tweak the chemistry of existing battery materials according to the precise needs of its cars.

Tesla claims that it is on track to produce a $35,000 electric car with a roughly 200-mile range by 2017—a feat that’s equivalent to what GM hoped to achieve with Envia’s new battery. The company anticipates selling hundreds of thousands of these electric cars a year, which would be a big leap from the tens of thousands it sells now. Yet for electric cars to account for a significant portion of the roughly 60 million cars sold each year around the world, batteries will probably need to get considerably better. After all, 200 miles is far short of the 350-plus miles people are used to driving on a tank of gasoline, and $35,000 is still quite a bit more than the $15,000 price of many small gas-powered cars.

How will we close the gap? There is probably still plenty of room to improve lithium-ion batteries, though it’s hard to imagine that Tesla’s success with minor changes to battery chemistry will continue indefinitely. At some point, radical changes such as the ones Envia envisioned may be needed. But the lesson from the Envia fiasco is that such changes must be closely integrated with manufacturing and engineering expertise.

That approach is already yielding promising results with the Argonne material that Envia licensed. Envia’s battery operated at high voltages to achieve high levels of energy storage. Now battery manufacturers are finding that using more modest voltage levels can significantly increase energy storage without the problems that troubled Envia. Meanwhile, battery researchers are publishing papers that show how trace amounts of additives change the behavior of the materials, making it possible to edge up the voltage and energy storage. The key is to combine research that illuminates details about the chemistry and physics of batteries with the expertise that battery manufacturers have gained in making practical products.

It’s an industry in which it’s very difficult for a startup, however enticing its technology, to go it alone. Andy Chu, a former executive at A123 Systems, which went bankrupt in 2012, recently told me why large companies dominate the battery industry. “Energy storage is a game played by big players because there are so many things that can go wrong in a battery,” he said. “I hope startups are successful. But you can look at the history over the past few years, and it’s not been good.”


TOPICS: News/Current Events
KEYWORDS: battery; electricity; energy
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To: Zathras
The key problem is Lithium is a fairly rare element.

Ecowhackos trading one earth element for another. The magic fix is not available
and will not be for another thousand years, or more. It doesn't exist and has not
even been contemplated yet.

Perfect earth utopian fantasy.

61 posted on 02/11/2015 7:35:25 AM PST by MaxMax (Pay Attention and you'll be pissed off too! FIRE BOEHNER, NOW!)
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To: thackney

Well there was a theory for awhile that said you could use superconductors to make electricity much more efficient by reducing the electrical resistance dramatically. The problem was temperature. If they ever find a workaround maybe that is the breakthrough needed. If you can run a vehicle using much less electricity then batteries become much less of a problem.


62 posted on 02/11/2015 7:36:57 AM PST by Mad Dawgg (If you're going to deny my 1st Amendment rights then I must proceed to the 2nd one...)
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To: Boiler Plate; duckworth

According to Star Trek Encyclopedia, lithium was originally used as the basis of power generation and warp technology. However it was soon realized that lithium is a real element with known properties. Dilithium was invented to allow for a fuel material with unknown properties. In the Star Trek: Enterprise episodes “The Augments” and “Affliction”, it is established that the NX-class Earth ships and the Klingon Bird-of-Prey in fact already used a dilithium matrix in the mid-22nd century.

Lithium in a crystal form was utilized in “lithium crystal circuits,” important components in the power-generation systems of Constitution-class starships. In order to be utilized in this fashion, lithium crystals were required to be processed in large “cracking stations,” such as the one on planet Delta Vega. (TOS: “Where No Man Has Gone Before”)

Overexpenditure of power could damage the lithium crystals, as happened to the Starship Enterprise in 2266, when chasing a Class-J starship into an asteroid belt. Forced to extend her shields around the vessel to protect it from asteroid collisions, the Enterprise burned out three of four lithium crystals, forcing the crew to supplement with battery power. The fourth crystal subsequently failed, overstressed from handling all of the ship’s power. (TOS: “Mudd’s Women”)

http://en.memory-alpha.org/wiki/Lithium_crystal


63 posted on 02/11/2015 7:41:11 AM PST by thackney (life is fragile, handle with prayer)
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To: thackney

Even tiny changes to the composition of a material can have a significant impact on performance, so for all Envia knew, its record-setting battery worked because of a contaminant in a batch of material from one of its suppliers.

...

The most probable explanation is that Envia committed fraud.


64 posted on 02/11/2015 7:42:10 AM PST by Moonman62 (The US has become a government with a country, rather than a country with a government.)
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To: thackney

That’s my meter.

I do miss the old Simpsons though.


65 posted on 02/11/2015 7:48:13 AM PST by MileHi (Liberalism is an ideology of parasites, hypocrites, grievance mongers, victims, and control freaks.)
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To: thackney

I agree... and once battery storage is vastly improved, solar power could actually start becoming more viable (rather than a tax-revenue-sucking failure). Here’s to hoping someone makes a few billion with a ground-breaking idea in this area soon!


66 posted on 02/11/2015 7:49:47 AM PST by Teacher317 (We have now sunk to a depth at which restatement of the obvious is the first duty of intelligent men)
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To: stremba

I would think that something like they do with propane tanks for gas grills could alleviate this somewhat. You have someone remove your battery and trade it for a fully charged one (for a fee, of course). That would likely take longer than a fill up with a gasoline-powered vehicle, but certainly not as long as charging the battery would take.

...

If the batteries are made standard and made easily removable, the process could be done with a simple robot, and take much less time than filling with gas.


67 posted on 02/11/2015 7:53:48 AM PST by Moonman62 (The US has become a government with a country, rather than a country with a government.)
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To: thackney

Even including the overhead of the pack enclosure, connections between cells in modules (and modules in the pack), sensors, and circuitry, Tesla likely has lower pack costs than any other maker of plug-in electric cars.

Simplifying a cheap cell

But for the Model S, Tesla redesigned what was already a relatively simple cell to be much less complex, and to have a much lower manufacturing cost—largely by removing expensive safety systems built into each individual cell.

When used as a laptop battery, each cells requires a safety mechanisms to prevent fires. But in a large, electronically-controlled, liquid-cooled battery pack like the one used in the Tesla Model S, having certain safety features on each cell would be redundant.

In this case, the company’s cell design eliminates the relatively complicated battery cap of the commercial cell, and replaces it with a simple aluminum disk.

Intumescent goo

Having radically simplified the cells, Tesla then designed simple and inexpensive fireproofing systems into its battery pack. Among many innovations, Tesla appears to have incorporated a form of intumescent goo that it sprays onto the interior of the pack to aid in fireproofing.

When exposed to heat, a chemical reaction occurs in the goo that helps cool the heat source, while simultaneously forming a fireproof barrier to protect the rest of the pack.

...

Kudos to Musk for figuring out what works and is commercially viable. I know the market is subsidized, but that won’t always be the case and he’s still doing a much better job than anyone else. He’s doing the same thing with rockets, too.

I wonder if Boeing has considered using the Tesla battery in the 787?


68 posted on 02/11/2015 7:58:51 AM PST by Moonman62 (The US has become a government with a country, rather than a country with a government.)
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To: Graybeard58

Connect the lightening rod to the car’s flux capacitor and you can get there in no time.


69 posted on 02/11/2015 8:00:16 AM PST by Vince Ferrer
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To: Graybeard58
Attach a lightening rod to the roof of a car to catch lightening bolts and somehow convert that energy to usable energy,

But you would have to be driving by at just the right time! :-)


70 posted on 02/11/2015 8:26:28 AM PST by mc5cents
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To: envisio

“You cannot get more out of something than you put in it.”

Talk to the welfare bunch. :-)


71 posted on 02/11/2015 8:31:49 AM PST by SgtHooper (Anyone who remembers the 60's, wasn't there!)
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To: Iron Munro
Liberals are so accustomed to breaking mankind’s laws they believe they should be able to break natural law with the same ease.

Bingo! Breaking or ignoring! Same ting.

72 posted on 02/11/2015 8:35:11 AM PST by mc5cents
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To: saleman

LOL!


73 posted on 02/11/2015 8:36:57 AM PST by mc5cents
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To: Boiler Plate

The problem with dilithium is that as it is more strongly energized the crystal structure breaks down faster. So going from warp four to warp six is hard on the crystals, but going from warp six to warp seven induces even more fracturing.


74 posted on 02/11/2015 8:40:29 AM PST by AceMineral (One day men will beg for chains.)
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To: thackney

Battery technology bump for later...


75 posted on 02/11/2015 8:52:45 AM PST by indthkr
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To: Iron Munro
the population will increasingly be concentrated into cities.

Self-driving cars will soon make it practical for the middle class to live 2 hours away from their jobs in the filthy cities. There already is an exodus out of the cities occurring, mostly white Americans. Because city governments always set up Ponzi style retirement programs, they are now scrambling to import people from third world countries to keep their Ponzi schemes going a little longer. In the northeast a substantial and growing percentage of all tax revenue goes straight to government retirees, many of them now receiving their tax loot far away in Florida. Economically that is unsustainable. The old cities are going bankrupt.

76 posted on 02/11/2015 9:18:35 AM PST by Reeses
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To: thackney; All
"Why We Don’t Have Battery Breakthroughs"



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77 posted on 02/11/2015 9:21:02 AM PST by musicman (Until I see the REAL Long Form Vault BC, he's just "PRES__ENT" Obama = Without "ID")
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To: musicman

Breakthrough of the protective outer casing wasn’t the goal in mind...


78 posted on 02/11/2015 9:29:47 AM PST by thackney (life is fragile, handle with prayer)
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To: thackney

I hear you,,, we’re working on it...


79 posted on 02/11/2015 9:54:56 AM PST by ßuddaßudd (>> F U B O << "What the hell kind of country is this if I can only hate a man if he's white?")
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To: thackney

There is already capacitor technology to charge very rapidly and store a huge amount of power using carbon nanotubes in forest-like arrays. The basic problem about to be solved is the measured drain of the charge.


80 posted on 02/11/2015 9:58:55 AM PST by MHGinTN (Is it really all relative, Mister Einstein?)
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