If you had any creditability at all you would answer the question. What article of the Constitution of the United States give a state a method of leaving the United States.
You were the one that claimed such a provision was in the Constitution. Put up or shut up. Obviously you have opted for the shut up mode due to a lack of knowledge of the subject you have tried to discuss and the Constitution of the United States. I guess the validity of the old adage that “ignorance is bliss” is substantiated by you.
Arguably Amendments 9 & 10
As there is nothing in the Constitution denying to the states the power to leave they must still retain it. (Such prohibitions are explicitly laid out: prohibition of ex post facto law, prohibition of entering into treaty/alliance/confederation, prohibition against bills of attainder, etc.)