Free Republic
Browse · Search
News/Activism
Topics · Post Article

Skip to comments.

Water-air interface barely there - Transition zone extremely thin
Science News ^ | June 9, 2011 | Rachel Ehrenberg

Posted on 06/09/2011 2:17:01 PM PDT by neverdem

Where sea meets sky, there are lots of water molecules with an identity crisis. About a quarter of the H2O in water’s uppermost layer can’t decide whether to be liquid or gas: One hydrogen atom stays in the drink while the other pokes up, vibrating in the air.

This layer of molecular ambiguity is extremely thin and has little or no effect on the water below it, new data reported June 9 in Nature show. Right beneath the liquid’s surface, water molecules go about their business just as if the air weren’t there.

That may seem like a dull discovery, but the find is important, says Pavel Jungwirth of the Academy of Sciences of the Czech Republic in Prague, who wrote a commentary on the work in the same issue of Nature.

“In some ways this is a negative result,” Jungwirth says. “Sometimes a negative result can be very positive.”

Insights into the behavior of water molecules at this superthin surface layer may give scientists a better understanding of the bonding and behavior of pollutants or other compounds intermingling at the surface. The new data might also improve models of water’s interactions with the atmosphere and within cells, says physical chemist Dennis Hore of University of Victoria in British Columbia, who was not involved in the study.

The finding that water molecules with one hydrogen waving in the air have little effect on the arrangement of all the H2O below refutes an idea that’s been bandied about for ages — that water molecules in bulk below will fall into lockstep, organizing themselves into orderly layers, says Jungwirth.

“After the first layer, it’s all over,” he says. “A lot of people still subscribe to this long-range idea. But this shows very clearly that you don’t have long-range order in. . ..”

(Excerpt) Read more at sciencenews.org ...


TOPICS: Culture/Society; News/Current Events; Testing
KEYWORDS: chemistry; hydrogenbonding; physicalchemistry; physicalchemistryw; physics; water
Hydrogen bonding at the water surface revealed by isotopic dilution spectroscopy

Physical chemistry: Water's wafer-thin surface

1 posted on 06/09/2011 2:17:06 PM PDT by neverdem
[ Post Reply | Private Reply | View Replies]

To: neverdem

Surface tension raises it’s forgotten head?


2 posted on 06/09/2011 2:20:18 PM PDT by OldNavyVet (One trillion days, at 365 days per year, is 2,739,726,027 years ... almost 3 billion years)
[ Post Reply | Private Reply | To 1 | View Replies]

To: neverdem

So it either is or isn’t, there is no in between.


3 posted on 06/09/2011 2:31:51 PM PDT by cripplecreek (Remember the River Raisin! (look it up))
[ Post Reply | Private Reply | To 1 | View Replies]

To: neverdem

As a scientist, I am embarrassed. I don’t think I’ve ever seen anything good come of a grant.


4 posted on 06/09/2011 2:45:15 PM PDT by Born to Conserve
[ Post Reply | Private Reply | To 1 | View Replies]

To: neverdem

Water evaporates. Who knew?


5 posted on 06/09/2011 2:57:58 PM PDT by bk1000 (A clear conscience is a sure sign of a poor memory)
[ Post Reply | Private Reply | To 1 | View Replies]

To: OldNavyVet

“Water still puzzles scientists” - just go to any water fountain at any research facility and you’ll find dozens of people in white lab coats going “oooh!” and “ahhhh!”.


6 posted on 06/09/2011 3:30:22 PM PDT by blueunicorn6 ("A crack shot and a good dancer")
[ Post Reply | Private Reply | To 2 | View Replies]

To: Born to Conserve

I will be asking for a grant to study why you can get 10 pounds of sh#t in a 5 pound bag, should be good for $250 large.


7 posted on 06/09/2011 3:51:08 PM PDT by Recon Dad (Herman Cain is the man in 2012)
[ Post Reply | Private Reply | To 4 | View Replies]

Disclaimer: Opinions posted on Free Republic are those of the individual posters and do not necessarily represent the opinion of Free Republic or its management. All materials posted herein are protected by copyright law and the exemption for fair use of copyrighted works.

Free Republic
Browse · Search
News/Activism
Topics · Post Article

FreeRepublic, LLC, PO BOX 9771, FRESNO, CA 93794
FreeRepublic.com is powered by software copyright 2000-2008 John Robinson