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I checked Army records for all Charles W. Payne’s and didn’t find his uncle:
34986135 PAYNE#CHARLES#W######### MISSISSIPPI ALCORN CP SHELBY MISSISSIPPI 44 Civil Life 24
35130575 PAYNE#CHARLES#W######### OHIO HIGHLAND STOUT FIELD INDIANAPOLIS INDIANA 45 Enlisted Man, Philippine Scout or recall to AD of an enlisted man who had been transferred to the ERC 18
35484733 PAYNE#CHARLES#W######### KENTUCKY GRAYSON LOUISVILLE KENTUCKY 42 Civil Life 15
35771823 PAYNE#CHARLES#W######### Undefined Code Undefined Code HUNTINGTON WEST VIRGINIA 43 Civil Life 24
35824855 PAYNE#CHARLES#W######### KENTUCKY JEFFERSON LOUISVILLE KENTUCKY 45 Civil Life 26
35986647 PAYNE#CHARLES#W######### OHIO KNOX FT BRAGG NORTH CAROLINA 45 Enlisted Man, Philippine Scout or recall to AD of an enlisted man who had been transferred to the ERC 24
38288470 PAYNE#CHARLES#W######### ARKANSAS VAN BURNE LITTLE ROCK ARKANSAS 42 Civil Life 22
39410090 PAYNE#CHARLES#W######### CALIFORNIA NAPA SACRAMENTO CALIFORNIA 43 Civil Life 23
39463879 PAYNE#CHARLES#W#JR###### IDAHO LATAH SPOKANE WASHINGTON 43 Civil Life 24
19047778 PAYNE#CHARLES#W######### OREGON MULTNOMAH PORTLAND OREGON 42 Civil Life 17
20349511 PAYNE#CHARLES#W######### MARYLAND HARFORE BALTIMORE MARYLAND 41 National Guard 18
00630346 PAYNE#CHARLES#W#######/# MICHIGAN GENESEE FLINT MICHIGAN 40 National Guard 17
32138878 PAYNE#CHARLES#W######### NEW YORK STEUBEN ROCHESTER NEW YORK 42 Civil Life 19
33132335 PAYNE#CHARLES#W######### VIRGINIA SPOTSYLVANIA CP LEE VIRGINIA 42 Civil Life 20
33812896 PAYNE#CHARLES#W######### Undefined Code Undefined Code PHILADELPHIA PENNSYLVANIA 44 Civil Life 16
34140857 PAYNE#CHARLES#W######### TENNESSEE KNOX FT OGLETHORPE GEORGIA 41 Civil Life 13
34255437 PAYNE#CHARLES#W######### NORTH CAROLINA PERSON FT BRAGG NORTH CAROLINA 42 Civil Life 20
34710694 PAYNE#CHARLES#W######### TENNESSEE KNOX CP FORREST TENNESSEE 43 Civil Life 23
34881456 PAYNE#CHARLES#W#SR###### TENNESSEE KNOX FT OGLETHORPE GEORGIA 43 Undefined Code 08