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Q&A: Liquid explosives
BBC News ^ | 08/10/06 | BBC News

Posted on 08/10/2006 9:49:54 AM PDT by Sax

Q&A: Liquid explosives

An alleged plot to blow up planes from the UK mid-flight and cause "mass murder on an unimaginable scale" has been disrupted, Scotland Yard has said. It is thought the plan was to detonate explosive devices smuggled in hand luggage on to as many as 10 aircraft.

BBC security correspondent Gordon Corera said the plan "revolved around liquids of some kind". One theory is that the attack may have involved liquid explosive being carried on to a plane in either drink bottles or cans. Dr Clifford Jones, an explosives expert from the University of Aberdeen, says even a small amount of liquid explosives carried on to an aircraft would result in a catastrophic explosion.

What are liquid explosives? The best place to start is with the term "high explosive"; these can be either solid or liquid. Of course, the most famous ones are solid, such as Dynamite and TNT.

One liquid explosive is a general use explosive that is used in quarries. However, I would not be surprised if it is possible to produce solid explosives in liquid form.

How do they work? Usually when something burns, it is subsonic and there is very little pressure effect. With high explosives, the rate of burning is extremely rapid and exceeds the speed of sound. As a result of that there is something called "overpressure" - pressure greater than the surrounding atmospheric pressure. Massive overpressure is not needed to cause damage. An excess of 1% can break windows, and an overpressure of 10% can harm or kill people and cause structural damage to buildings. An overpressure of just 2% could break the windows of the aeroplane, and 10% would wreck the aircraft and possibly kill the people in it before it reached the ground. By the time the damage is caused, the chemistry has finished and physics has taken over.

How are they made? There are such things as liquid explosives that are high explosives and they behave in exactly the same way as solid explosives, such as TNT. But there are also explosives that are made by mixing a solid and a liquid - one being the oxidant and the other being the fuel. Unlike most high explosives, they do not contain the fuel and oxidant in the same molecule but they do contain them in sufficiently close contact to cause a blast.

Are the components difficult to get hold of? No, it is very easy. Ordinary household substances could be used. Specialist knowledge or equipment needed to make? If someone wanted to obtain a solid high explosive in a liquid form, it would not be difficult for a trained chemical technologist. But if someone was using a backyard laboratory it is more likely they would go for the two component approach. Not a lot of experience is needed, the principles are quite simple but it would be a hazardous process of trial and error. I would not want to be messing about these things. It has been known for schoolboys to go home and attempt this and blow their house up.

Could an explosive device be carried on to an aeroplane? The size of a device necessary could be carried in hand baggage. Explosives in a toilet bag, certainly inside a shoulder bag would be enough to meet the terrorists' needs. They could be quite hard to detect because I do not think any of the things we have mentioned would respond to x-rays. For example, a liquid hydrocarbon fuel could pass as mineral water.

The question is how do you get something packed into a bag so it does not look suspicious?


TOPICS: Crime/Corruption; Foreign Affairs; News/Current Events; United Kingdom; War on Terror
KEYWORDS: explosive; liquid; liquids; londonairlineplot; nitro
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It's no longer the old lady's nail clippers, it's someone's bottled water that could be the real danger.

Say good bye to carry on luggage.

1 posted on 08/10/2006 9:49:55 AM PDT by Sax
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To: Sax

Ramzi Usef was working on a binary liquid explosive in the Phillipenes, after he did the first World Trade Center bombing (1995, 96). He lit the apartment building on fire.

The plan was named Bojinka and involved sneaking a liquid explosive on at least ten planes and blowing them up all on the same day.

Once a plan gets gelled, looks like they don't let go of it.


2 posted on 08/10/2006 9:54:43 AM PDT by DBrow
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To: Sax
The question is how do you get something packed into a bag so it does not look suspicious?

Impossible to stop really. All the terrorists need to do is what the drug couriers routinely do. I can see stool checks before boarding next.

3 posted on 08/10/2006 9:54:45 AM PDT by beltfed308 (Nanny Statists are Ameba's.)
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To: Sax

Damn terrorists.


4 posted on 08/10/2006 9:54:51 AM PDT by psjones
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To: Sax

Sir, you'll have to remove the colostomy bag before boarding.


5 posted on 08/10/2006 9:55:11 AM PDT by cripplecreek (If stupidity got us into this mess, then why can't it get us out?)
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To: Sax
When I hear of liquid explosives, I think of nitroglycerin and the episode of Bonanza where they had to transport a wagon load of it across the mountains. (If I recall, they used a hearse because of its cushy suspension.) Jostle the nitroglycerin too much, and they'd all be blown to smithereens.
6 posted on 08/10/2006 9:55:19 AM PDT by newgeezer ("Hezbollah" is a deception. As they are the 'party of Allah', the accurate rendering is "Hezb'Allah")
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To: Sax
Has this writer totally forgotten about nitro? An easy explosive to make, albeit very dangerous, to make it at home would usually require a bathtub full of ice, but it can be done and then simply keep it cool when transporting.

I would think, however, that nitro would not be the first choice, it is very unstable, at the same time a very small amount would take out an airplane.

7 posted on 08/10/2006 9:56:19 AM PDT by calex59 (The '86 amnesty put us in the toilet, now the senate wants to flush it!)
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To: DBrow

Anybody remember the third Die Hard?


8 posted on 08/10/2006 9:56:36 AM PDT by 50sDad (ST3d: Real Star Trek 3d Chess: http://my.ohio.voyager.net/~abartmes/tactical.htm)
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To: Sax
Say good bye to carry on luggage.

Listening to the news this morning, I heard a traveler tell a reporter that the TSA agent would have to forcefully remove liquid from her bags. There was no way she would!!

The muzzies are not fooling around. They are like internet hackers who have lots and lots of time to scheme and plan.

9 posted on 08/10/2006 9:57:53 AM PDT by llevrok (When you take my gin from my cold, dead hand....)
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To: newgeezer
I bet they let Hop Sing drive the hearse too.
10 posted on 08/10/2006 9:58:48 AM PDT by llevrok (When you take my gin from my cold, dead hand....)
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To: Sax
I note that the author was very careful to avoid specifics....

We'll be fine as long as the terrorists keep going for the uber-spectacular. It's when they take up lower-yield but perhaps more frequent insurgency tactics that things will get ugly.

11 posted on 08/10/2006 9:59:00 AM PDT by r9etb
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To: Sax
Say good bye to carry on luggage.

You are most probably right, but I am at a complete loss why having a two quarts of binary liquid explosive in the hold is any safer than having it in the cabin.
12 posted on 08/10/2006 9:59:13 AM PDT by Deek
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To: Sax

Drats! There goes my hair gel, my bottle of water, my shampoo, my creams, my acne salve, etc. Dang! Dang! Dang! Dang!


13 posted on 08/10/2006 9:59:19 AM PDT by lilylangtree
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To: cripplecreek
Sir, you'll have to remove the colostomy bag before boarding.

It'll have to be corked for the duration of the flight.

14 posted on 08/10/2006 9:59:58 AM PDT by Sax (You Done Tore Out My Heart And Stomped That Sucker Flat)
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To: newgeezer
... the episode of Bonanza where they had to transport a wagon load of it across the mountains....

That was an episode of The Big Valley, IIRC....

15 posted on 08/10/2006 10:00:01 AM PDT by r9etb
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To: Sax
A new terrorist explosive, triacetone triperoxide (TATP), has recently appeared as a weapon in the Middle East. TATP has been used by suicide bombers in Israel, and was chosen as a detonator in 2001 by the thwarted "shoe bomber" Richard Reid. It can be as or more powerful than military analogs. TATP is one of the most sensitive explosives known, being extremely sensitive to impact, temperature change and friction. Another peroxide-type explosive is hexamethylene triperoxide diamine (HMTD), which is less sensitive than TATP but still dangerous. HMTD is somewhat more sensitive to impact than TCPT, but both are very sensitive explosives. The explosion of TATP is not a thermochemically highly favored event. In conventional high explosives such as TNT, each molecule contains both a fuel component and an oxidising component. When the explosive detonates, the fuel part is oxidised and as this combustion reaction spreads it releases large amounts of heat. The explosion of TATP involves entropy burst, which is the result of formation of one ozone and three acetone molecules from every molecule of TATP in the solid state. Just a few hundred grams of the material produce hundreds of litres of gas in a fraction of a second. The explosion of TATP is similar to the decomposition of azide, for example, which produces nitrogen gas but little heat, is used to fill airbags for cars. TATP is the most extreme example currently known, but it may be possible to design molecules that behave as an even more powerful explosive. TATP can be easily prepared in a basement lab using commercially available starting materials obtained from, e.g., hardware stores, pharmacies, and stores selling cosmetics. TATP is a fairly easy explosive to make, as far as explosives manufacturing goes. All it takes is acetone, hydrogen peroxide (3% medicinal peroxide is not concentrated enough), and a strong acid like hydrochloric or sulfuric acid. I don't recommended mixing up a batch for Independence Day celebrations because it's easy to blow yourself up when you make it.

Source http://www.globalsecurity.org/military/systems/munitions/tatp.htm

16 posted on 08/10/2006 10:00:40 AM PDT by Ben Mugged
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To: newgeezer

Binary systems like glycerine or sugar and permanganate or perchlorate can make a nasty explosion.

These were used by the resistance in WW2.


17 posted on 08/10/2006 10:02:45 AM PDT by BillM
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To: Deek
You are most probably right, but I am at a complete loss why having a two quarts of binary liquid explosive in the hold is any safer than having it in the cabin.

Yeah with a keychain remote.

18 posted on 08/10/2006 10:02:50 AM PDT by Sax (You Done Tore Out My Heart And Stomped That Sucker Flat)
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To: Deek

They probably can make luggage containers that can contain a small blast.


19 posted on 08/10/2006 10:03:27 AM PDT by Names Ash Housewares
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To: 50sDad

That was the first reference that came to mind.


20 posted on 08/10/2006 10:03:52 AM PDT by Larry Lucido
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