A few months ago, a 400 foot hole opened up in a tunnel containing rail cars filled with radioactive waste (Hanford, WA). But it’s not the only problem there and just glancing around I found this from 2 years ago:
“On Dec. 10, radioactive contamination was found on the elbow of a worker after the suit had been removed. It was one of several incidents at the Plutonium Finishing Plant during the past six months, including incidents of skin contamination.”
http://www.tri-cityherald.com/news/local/hanford/article50600355.html
Sounds like there may have been some residual moisture and/or nitric acid left in the powder, and radiolysis of the moisture by the plutonium's alpha radiation resulted in the production of hydrogen or nitrogen oxide gas. The gas pressure in the sealed container caused some of the radioactive powder to blow out when the lid of the container was unbolted. The main danger is worker inhalation of the plutonium dust as blew out of the container. External radiation is minor for that amount of plutonium or uranium.