So, nothing after Ye shall not add unto the word which I command you, neither shall ye diminish ought from it, that ye may keep the commandments of the LORD your God which I command you. (Deuteronomy 4:2) Is valid?
Man is never to add to God's word.
However, God does not limit Himself on how much He may speak.
So, yes, everything God added after that verse i Deuteronomy IS valid, and no, nothing man added since then is valid. Stuff man adds never is.