1. Buy new, by American, if possible. You can't trust a used mask. It's a simple setup, but why take the risk when your life depends on it.
2. The most important feature is that canister you are questioning. It MUST be able to protec you against the appropriate agents, in my case all known NBC, and it MUST be in reasonable condition. You can identify the age of most cannisters by the serial/production number. If it's a 3M cannister you'll find many websites that help you identify the production age.
Also, make sure you have the Tyvek suits to go along with it, or you might be surviving long enough to watch your skin melt.