Astrophysics. I have never heard ANY astrophysicist say conclusively and unequivocally that we humans here on Earth are the only form of life in the universe. If this universe, with more galaxies in it then there are grains of sand on a beach and to think that if you were to scoop up a handful of that sand and see only one blue and white grain of sand, then you and anyone else is a moron.
Now why do plants pump out oxygen? It requires quite a bit of energy to bust up the water molecule to liberate oxygen yet after doing so the plant just throws this juicy bit of chemical energy away. Normally nature tries to minimize energy usage but in this case it was so wasteful nature succeeded in saturating an entire planet with the stuff! It must have required some extreme bit of luck to lock plants into such a wasteful expenditure of energy.
Oxygen reactions are so energetic they not only make fire possible it gives animals enough energy to move around. Its this ability to move around and explore things that makes intelligent life a possibility. Plants are not known for their intelligence.
So far over 4000 exoplanets have been discovered . On one confirmed planet that had elemental oxygen , it was on a world so hot and close to its star the abundance of high energy was busting up molecules with oxygen.
I suspect its going to take looking at a lot more worlds before we ever find one with oxygen on it like Earth has.Perhaps mankind will someday find a world with elemental fluorine in its atmosphere, but Im pretty sure Im not going to be around to see that either.